Crystal structure of the coordination polymer [Cu2(S-mal)2(bpy)2(H2O)]•2.5H2O

被引：4
|
作者：
Zavakhina, M. S. [1 ,2 ]
Samsonenko, D. G. [1 ,2 ]
Fedin, V. P. [1 ,2 ]
机构：
[1] Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Novosibirsk, Russia
[2] Novosibirsk Natl Res State Univ, Novosibirsk, Russia
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2015年 / 56卷 / 01期
关键词：
copper; coordination polymers; metal-organic frameworks; chiral complexes; malic acid; METAL-ORGANIC FRAMEWORKS; TOPOLOGIES;
D O I：
10.1134/S0022476615010151
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
In the interaction of basic copper carbonate with optically pure malic acid and 4,4'-bipyridine [Cu-2(S-mal)(2)(bpy)(2)(H2O)]center dot 2.5H(2)O (1) is obtained. The structure of the metal-organic coordination polymer is unique for this class of compounds, which is established by the single crystal X-ray diffraction analysis using synchrotron radiation.
引用
收藏
页码：108 / 112
页数：5
相关论文
共 50 条
  • [1] Crystal structure of the coordination polymer [Cu2(S-mal)2(bpy)2(H2O)]·2.5H2O
    M. S. Zavakhina
    D. G. Samsonenko
    V. P. Fedin
    Journal of Structural Chemistry, 2015, 56 : 108 - 112
  • [2] CRYSTAL STRUCTURE OF METAL-ORGANIC COORDINATION POLYMERS [Cu(bpy)2(H2O)2](NO3)2•4.5C2H5OH AND [Cu2(bpy)(H2O)(L-pha)2](NO3)2•H2O
    Yutkin, M. P.
    Zavakhina, M. S.
    Samsonenko, D. G.
    Fedin, V. P.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2011, 52 (02) : 365 - 370
  • [3] Crystal structure of metal-organic coordination polymers [Cu(bpy) 2(H2O)2](NO3)2·4. 5C2H5OH and [Cu2(bpy)(H2O)(L-pha) 2](NO3)2·H2O
    Yutkin M.P.
    Zavakhina M.S.
    Samsonenko D.G.
    Fedin V.P.
    Journal of Structural Chemistry, 2011, 52 (2) : 365 - 370
  • [4] Crystal structures of [Cu2(bpy)2(H2O)(OH)2(SO4)] • 4H2O and [Cu(bpy)(H2O)2]SO4 with bpy=2,2′-bipyridine
    Zheng, YQ
    Lin, JL
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2003, 629 (09): : 1622 - 1626
  • [5] Synthesis, spectral, thermal and structural characterization of {[Cu(H2O)3][Cu(MAL)2] · 2H2O}∞ and [Cu(MAL)(TEA)] · H2O (MAL = malonate and TEA = triethanolamine)
    Veysel T. Yilmaz
    Evrim Senel
    Carsten Thöne
    Transition Metal Chemistry, 2004, 29 : 336 - 342
  • [6] Synthesis, crystal structure and magnetic properties of a chain coordination polymer {[Cu4L2(H2O)] • H2O}n
    Tao, RJ
    Li, FA
    Cheng, YX
    Zang, SQ
    Wang, QL
    Niu, JY
    Liao, DZ
    INORGANICA CHIMICA ACTA, 2006, 359 (07) : 2053 - 2058
  • [7] Crystal structure of [Cu2(L)2(H2O)2](SO4)2•2H2O (L = pyridoxal thiosemicarbazone)
    Rodic, Marko V.
    Leovac, Vukadin M.
    Vojinovic-Jesic, Ljiljana S.
    Cesljevic, Valerija I.
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2011, 67 : C607 - C608
  • [8] Crystal structures of three copper(II)-2,2′-bipyridine (bpy) compounds, [Cu(bpy)2(H2O)][SiF6]•4H2O, [Cu(bpy)2(TaF6)2] and [Cu(bpy)3][TaF6]2 and a related coordination polymer, [Cu(bpy)(H2O)2SnF6]n
    Nisbet, Matthew L.
    Hiralal, Emily
    Poeppelmeier, Kenneth R.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2021, 77 : 158 - +
  • [9] Synthesis, Crystal Structure, Magnetic Property and DFT Study of a Novel 2D Polymer [Cu(pdc)(bpy)•H2O
    Guo Rui
    Qi Xi-Wei
    Xie Cheng-Zhi
    Zhong Bing-Wen
    Liu Xuan-Wen
    Zhang Yue-Hong
    Su Na
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2014, 33 (02) : 270 - 276
  • [10] Ternary copper(II) malonato complexes with alkali metals:: K2Cu(mal)2 • 3H2O, Rb2Cu(mal)2 • H2O, Cs2[Cu(H2O)2(mal)2] 2H2O
    Zheng, Yue-Qing
    Ying, Er-Bo
    JOURNAL OF COORDINATION CHEMISTRY, 2006, 59 (11) : 1281 - 1293
12345