The Influence of Hydrogen-Bond Defects on the Properties of Ionic Liquids

被引：114
|
作者：
Peppel, Tim [1 ]
Roth, Christian [2 ]
Fumino, Koichi [2 ]
Paschek, Dietmar [2 ]
Koeckerling, Martin [1 ]
Ludwig, Ralf [2 ,3 ]
机构：
[1] Univ Rostock, Inst Chem, Abt Anorgan Chem, D-18059 Rostock, Germany
[2] Univ Rostock, Inst Chem, Phys Chem Abt, D-18059 Rostock, Germany
[3] Univ Rostock eV, Leibniz Inst Katalyse, D-18059 Rostock, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 29期
关键词：
ab initio calculations; crystal structures; hydrogen bonding; ionic liquids; melting points; MELTING-POINTS; TEMPERATURE; CATION; PREDICTION; BROMIDES; SALTS;
D O I：
10.1002/anie.201100199
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Counterintuitive: The preformation of ion pairs can explain the low melting points of imidazolium-based ionic liquids (ILs) and the resulting expanded range of working temperatures. This quasi-ion-pair formation is possible for ILs having cations with only one interaction site leading to local and directional hydrogen bonds with the corresponding anion (see structure; O red, N blue, F green, S yellow). Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：6661 / 6665
页数：5
相关论文
共 50 条
  • [1] Hydrogen-bond acidity of ionic liquids: an extended scale
    Kurnia, Kiki A.
    Lima, Filipa
    Claudio, Ana Filipa M.
    Coutinho, Joao A. P.
    Freire, Mara G.
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2015, 17 (29) : 18980 - 18990
  • [2] INFLUENCE OF HYDROGEN-BOND CONNECTIVITY ON THE DYNAMICAL PROPERTIES OF HYDROGEN-BONDED LIQUIDS
    MIGLIARDO, P
    JOURNAL OF MOLECULAR STRUCTURE, 1993, 296 (03) : 229 - 242
  • [3] Extended scale for the hydrogen-bond basicity of ionic liquids
    Claudio, Ana Filipa M.
    Swift, Lorna
    Hallett, Jason P.
    Welton, Tom
    Coutinho, Joao A. P.
    Freire, Mara G.
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2014, 16 (14) : 6593 - 6601
  • [4] Hydrogen-bond rich ionic liquids with hydroxyl cationic tails
    Deng, Li
    Shi, Rui
    Wang, Yanting
    Ou-Yang, Zhong-Can
    CHEMICAL PHYSICS LETTERS, 2013, 560 : 32 - 36
  • [5] Phonon-like Hydrogen-Bond Modes in Protic Ionic Liquids
    Reichenbach, Judith
    Ruddell, Stuart A.
    Gonzalez-Jimenez, Mario
    Lemes, Julio
    Turton, David A.
    France, David J.
    Wynne, Klaas
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (21) : 7160 - 7163
  • [6] HYDROGEN-BOND ACCEPTOR ABILITIES OF TETRACHLOROMETALATE(II) COMPLEXES IN IONIC LIQUIDS
    HITCHCOCK, PB
    SEDDON, KR
    WELTON, T
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (17): : 2639 - 2643
  • [7] Alternative probe for the determination of the hydrogen-bond acidity of ionic liquids and their aqueous solutions
    Madeira, Pedro P.
    Passos, Helena
    Gomes, Joana
    Coutinho, Joao A. P.
    Freire, Mara G.
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2017, 19 (18) : 11011 - 11016
  • [8] CONFORMATIONAL INFLUENCE ON HYDROGEN-BOND
    PLASS, M
    KOLBE, A
    JOURNAL OF MOLECULAR STRUCTURE, 1992, 267 : 21 - 32
  • [9] Hydrogen-bond dynamics of water in ionic solutions
    Bakker, HJ
    Kropman, MF
    Omta, AW
    Woutersen, S
    PHYSICA SCRIPTA, 2004, 69 (06) : C14 - C24
  • [10] The influence of hydrogen bonding on the physical properties of ionic liquids
    Fumino, Koichi
    Peppel, Tim
    Geppert-Rybczynska, Monika
    Zaitsau, Dzmitry H.
    Lehmann, Jochen K.
    Verevkin, Sergey P.
    Koeckerling, Martin
    Ludwig, Ralf
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2011, 13 (31) : 14064 - 14075
12345