Enhanced Li storage performance of ordered mesoporous MoO2 via tungsten doping

被引:60
作者
Fang, Xiangpeng [2 ]
Guo, Bingkun [2 ]
Shi, Yifeng [1 ]
Li, Bin [1 ]
Hua, Chunxiu [2 ]
Yao, Chaohua [1 ]
Zhang, Yichi [3 ]
Hu, Yong-Sheng [2 ]
Wang, Zhaoxiang [2 ]
Stucky, Galen D. [3 ]
Chen, Liquan [2 ,4 ]
机构
[1] Hangzhou Normal Univ, Coll Mat Chem & Chem Engn, Hangzhou 310036, Zhejiang, Peoples R China
[2] Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100080, Peoples R China
[3] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA
[4] Chonnam Natl Univ, Sch Mat Sci & Engn, Kwangju 500757, South Korea
基金
美国国家科学基金会;
关键词
LITHIUM-ION BATTERIES; ANODE MATERIAL; SECONDARY BATTERIES; NEGATIVE-ELECTRODE; NANOWIRE ARRAYS; TIO2; INTERCALATION; BETA-MNO2; CAPACITY; ANATASE;
D O I
10.1039/c2nr12017h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ordered mesoporous tungsten-doped MoO2 was synthesized by a nanocasting method. The Li storage performance of mesoporous MoO2 is significantly improved by tungsten doping, which exhibits a reversible capacity of 700 mA h g(-1), better cycling and rate performance. This material combines the advantages of the high theoretical capacity of MoO2 and the better electroactivity of WO2.
引用
收藏
页码:1541 / 1544
页数:4
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