Production of Renewable Aromatic Compounds by Catalytic Fast Pyrolysis of Lignocellulosic Biomass with Bifunctional Ga/ZSM-5 Catalysts

被引：269

作者：

Cheng, Yu-Ting ^{[1
]}

Jae, Jungho ^{[1
]}

Shi, Jian ^{[1
]}

Fan, Wei ^{[1
]}

Huber, George W. ^{[1
]}

机构：

[1] Univ Massachusetts, Goessmann Lab 159, Amherst, MA 01003 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 06期

基金：

美国国家科学基金会;

关键词：

arenes; biomass; catalytic fast pyrolysis; fuels; zeolites; SPOUTED-BED REACTOR; ZEOLITE CATALYSTS; VAPORS; FUELS; GASOLINE; SAWDUST; HZSM-5; NANOPOWDER; CONVERSION; CHEMICALS;

D O I：

10.1002/anie.201107390

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Burn, baby, burn! A new bifunctional catalyst (Ga/ZSM-5) displays increased selectivity for the production of aromatic compounds during the catalytic fast pyrolysis of biomass. With this Ga-promoted ZSM-5 catalyst, olefins such as ethylene and propylene, which are produced as intermediates, are more efficiently converted into aromatic compounds, especially benzene. Ga/ZSM-5 also promotes decarbonylation and olefin-aromatization reactions. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1387 / 1390

页数：4

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