Some practical tools for everyday least squares

被引:8
作者
Minguzzi, P [1 ]
机构
[1] Univ Pisa, Dipartimento Fis, Pisa, Italy
[2] Ist Nazl Fis Mat, Pisa, Italy
关键词
D O I
10.1006/jmsp.2001.8404
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
A few issues often encountered in least-squares estimation are discussed. A simple and general test for the goodness of fit is proposed, and an adaptive criterion for testing the convergence of iterative nonlinear problems is suggested. The old problem of the number of significant digits of correlated parameters is addressed and a new algorithm for rounding the numerical values is described. The underlying principles are emphasized and the accent is on practical implementation of improvements to computer codes for data analysis. (C) 2001 Academic Press.
引用
收藏
页码:169 / 177
页数:9
相关论文
共 18 条
[1]  
ALBRITTON DL, 1976, MOL SPECTROSCOPY MOD, V2, P1
[2]   The molecular constants of 12CH3I in the ground and ν6=1 excited vibrational state [J].
Carocci, S ;
Di Lieto, A ;
De Fanis, A ;
Minguzzi, P ;
Alanko, S ;
Pietila, J .
JOURNAL OF MOLECULAR SPECTROSCOPY, 1998, 191 (02) :368-373
[3]   MERGING OF LEAST-SQUARES PARAMETERS - APPROACH OF STEPWISE MERGING [J].
COXON, JA .
JOURNAL OF MOLECULAR SPECTROSCOPY, 1978, 72 (02) :252-263
[4]  
DURBIN J, 1950, BIOMETRIKA, V37, P409, DOI 10.1093/biomet/37.3-4.409
[5]   INTERDEPENDENCE OF PARAMETERS IN SPECTROSCOPIC DATA REDUCTION [J].
FEMENIAS, JL .
JOURNAL OF MOLECULAR SPECTROSCOPY, 1990, 144 (01) :212-223
[6]   ANALYSIS OF RESIDUALS IN FITTING SPECTROSCOPIC DATA [J].
FEMENIAS, JL ;
CHEVAL, G .
CANADIAN JOURNAL OF PHYSICS, 1992, 70 (2-3) :152-163
[7]  
KENDALL MG, 1955, ADV THEORY STAT, V2, P124
[8]   CODATA recommended values of the fundamental physical constants: 1998 [J].
Mohr, PJ ;
Taylor, BN .
REVIEWS OF MODERN PHYSICS, 2000, 72 (02) :351-495
[9]   ROUNDING LEAST-SQUARES PARAMETERS FOR PUBLICATION [J].
TELLINGHUISEN, J .
JOURNAL OF MOLECULAR SPECTROSCOPY, 1989, 137 (01) :248-250
[10]   ON THE LEAST-SQUARES FITTING OF CORRELATED DATA - REMOVING THE CORRELATION [J].
TELLINGHUISEN, J .
JOURNAL OF MOLECULAR SPECTROSCOPY, 1994, 165 (01) :255-264