Cobalt sulfide nanosheets coated on NiCo2S4 nanotube arrays as electrode materials for high-performance supercapacitors

被引：168

作者：

Fu, Wenbin ^{[1
]}

Zhao, Changhui ^{[1
]}

Han, Weihua ^{[1
]}

Liu, Ying ^{[1
]}

Zhao, Hao ^{[1
]}

Ma, Yufang ^{[1
]}

Xie, Erqing ^{[1
]}

机构：

[1] Lanzhou Univ, Sch Phys Sci & Technol, Lanzhou 730000, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2015年 / 3卷 / 19期

基金：

中国国家自然科学基金;

关键词：

NANOWIRE ARRAYS; NANOSTRUCTURED MATERIALS; NICKEL FOAM; NI FOAM; GENERATION; SUBSTRATE; DESIGN; GROWTH; FIBER;

D O I：

10.1039/c5ta00742a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Hierarchical hybrid electrodes were successfully fabricated by electrodeposition of ultrathin cobalt sulfide (CoSx) nanosheets on NiCo2S4 nanotube arrays grown on Ni foam for high-performance supercapacitors. The hierarchical NiCo2S4@CoSx core/shell nanotube arrays exhibit a high areal capacitance (4.74 F cm(-2) at a current density of 5 mA cm(-2)), a good rate capability (2.26 F cm(-2) at 50 mA cm(-2)) and cycle stability (76.1% capacitance retention after 1500 cycles at a high current density of 50 mA cm(-2)), which are much better than those of NiCo2S4 nanotubes. Such superior electrochemical performance could be attributed to the smart configuration of the two electroactive materials, which can provide more pathways for electron transport and improve the utilization rate of the electrode materials. This effective strategy shows the feasibility of designing and fabricating metal sulfides with core/shell hybrid structures as electrode materials for high-performance supercapacitors.

引用

页码：10492 / 10497

页数：6

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