Organophosphorus compounds. Part 163: Reactivity of phosphaalkynes towards in situ-generated titanium imido complexes

被引：6

作者：

Asmus, SMF ^{[1
]}

Regitz, M ^{[1
]}

机构：

[1] Univ Kaiserslautern, Fachbereich Chem, D-67663 Kaiserslautern, Germany

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 43期

关键词：

D O I：

10.1016/S0040-4039(01)01351-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of kinetically stabilized phosphaalkynes 5 in toluene with primary amines 4 in the presence of equimolar amounts of cyclopentadienyltitaniumtrichloride (2) leads to azaphosphatitanacyclobutane species 6. The formation of compounds 6 enables a first insight into the mechanism of the reaction of titanium imides with phosphaalkynes, presented in several recent papers. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：7543 / 7545

页数：3

共 14 条

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