Ruthenium-catalyzed Formation of Tertiary Amines from Nitrites and Alcohols

被引：17
作者：
Liu, Saiwen [1 ]
Chen, Ru [1 ]
Deng, Guo-Jun [1 ]
机构：
[1] Xiangtan Univ, Coll Chem, Minist Educ, Key Lab Environm Friendly Chem & Applicat, Xiangtan 411105, Peoples R China
来源：
CHEMISTRY LETTERS | 2011年 / 40卷 / 05期
基金：
中国国家自然科学基金;
关键词：
C-H BONDS; ANTI-MARKOVNIKOV HYDROAMINATION; N-ALKYLATION; BORROWING HYDROGEN; TRANSITION-METAL; INTERMOLECULAR HYDROAMINATION; SELECTIVE SYNTHESIS; SECONDARY-AMINES; AMINATION; ANILINES;
D O I：
10.1246/cl.2011.489
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A ruthenium-catalyzed tertiary-amine formation was developed using the borrowing hydrogen strategy. Various tertiary amines were obtained efficiently from nitrites and primary alcohols. Two possible pathways were found for the tertiary-amine formation under RuCl3/dppf catalytic conditions. The nitrites mainly act as a nitrogen source in this kind of transformation.
引用
收藏
页码：489 / 491
页数：3
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