Asymmetric induction in organic photochemistry via the solid-state ionic chiral auxiliary approach

被引：60

作者：

Scheffer, JR ^{[1
]}

Xia, WJ ^{[1
]}

机构：

[1] Univ British Columbia, Dept Chem, Vancouver, BC V6T 1Z1, Canada

来源：

ORGANIC SOLID STATE REACTIONS | 2005年 / 254卷

关键词：

asymmetric induction; organic photochemistry; solid state; ionic chiral auxiliaries; crystal structure-reactivity correlations;

D O I：

10.1007/b101000

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

After a brief introduction and summary of various methods of asymmetric induction in organic photochemistry, the main part of the review covers the solid-state ionic chiral auxiliary approach to asymmetric photochemical synthesis. Application of this technique to the Norrish type II reaction, as well as to the di-Ti-methane and oxa-di-pi-methane photorearrangements, and the Cis, trans-photoisomerization of diarylcyclopropane derivatives is presented and discussed.

引用

页码：233 / 262

页数：30

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