Carbazole-functionalized V-shaped bis-coumarin derivatives as organic luminescent materials

被引:8
作者
Li, Peiying [1 ]
Su, Ruige [2 ]
Zhang, Di [1 ]
Han, Minghu [1 ]
Zhao, Yuling [2 ]
Ma, Lishan [2 ]
Zhang, Hui [1 ]
Yu, Tianzhi [1 ]
机构
[1] Lanzhou Jiaotong Univ, Minist Educ, Key Lab Optoelect Technol & Intelligent Control, Lanzhou 730070, Peoples R China
[2] Lanzhou Jiaotong Univ, Sch Chem & Chem Engn, Lanzhou 730070, Peoples R China
基金
中国国家自然科学基金;
关键词
Synthesis; Bis-coumarin derivative; Carbazole; Photoluminescence; Electroluminescence; LIGHT-EMITTING-DIODES; RATIONAL DESIGN; EFFICIENCY; BLUE; MOLECULES; GREEN; DYE; OXADIAZOLE; EMITTERS; OLEDS;
D O I
10.1016/j.synthmet.2022.117069
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Two novel functionalized V-shaped bis-coumarin derivatives, namely CC-Cz and CC-2Cz, were successfully synthesized and characterized. The thermal stability, photophysical and electrochemical properties of the compounds were investigated systematically. By combining theoretical and experimental investigation, to reveal the structure-property relationships of different substituted coumarin-fused coumarins. These compounds possess good thermal stability with decomposition temperature over 360 ?, and exhibit strong green emission in solution and solid thin films. The solution-processed doped devices using the blend of PVK:PBD with the V-shaped bis-coumarin derivatives as emitting layers emit green emission with maximum external quantum efficiency (EQE(max)) of 2.20% for CC-2Cz , 1.98% for CC-Cz.
引用
收藏
页数:9
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