Photocatalytic Oxidation of 5-Hydroxymethylfurfural Over Interfacial-Enhanced Ag/TiO2 Under Visible Light Irradiation

被引：54

作者：

Zhang, Weizi ^{[1
]}

Li, Xinxin ^{[2
]}

Liu, Shaoru ^{[1
]}

Qiu, Jianhao ^{[1
]}

An, Jiahuan ^{[1
]}

Yao, Jianfeng ^{[1
]}

Zuo, Songlin ^{[1
]}

Zhang, Bo ^{[2
]}

Xia, Haian ^{[1
]}

Li, Changzhi ^{[2
]}

机构：

[1] Nanjing Forestry Univ, Jiangsu Coinnovat Ctr Efficient Proc & Utilizat F, Nanjing 210037, Peoples R China

[2] Chinese Acad Sci, Dalian Inst Chem Phys, CAS Key Lab Sci & Technol Appl Catalysis, Dalian 116023, Peoples R China

来源：

CHEMSUSCHEM | 2022年 / 15卷 / 13期

基金：

中国国家自然科学基金;

关键词：

5-hydroxymethylfurfural; biomass conversion; heterogeneous catalysis; nanoparticles; photocatalysis; METAL-SUPPORT INTERACTIONS; SELECTIVE OXIDATION; AEROBIC OXIDATION; 2,5-FURANDICARBOXYLIC ACID; CATALYSTS; AG; 2,5-DIFORMYLFURAN; ENERGY;

D O I：

10.1002/cssc.202102158

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Photocatalytic conversion of biomass-derived 5-hydroxyfurfural (HMF) to value-added 5-hydroxymethyl-2-furancarboxylic acid (HMFCA) is an environmentally friendly process. Here, Ag nanoparticle (NP) supported on TiO2 (Ag/TiO2) materials with different interfacial structures were fabricated via incipient wetness impregnation. In the photocatalytic oxidation of 5-HMF to HMFCA, low-temperature reduction (473 K) on Ag/TiO2 could improve the photoinduced charge separation efficiency and promote the reaction due to the "enhanced" localized surface plasmon resonance (LSPR) effects achieved through strong metal-support interaction (SMSI). In particular, 2.5 % Ag/TiO2-LTR exhibited superior performance with an HMFCA selectivity of up to 96.7 % under visible-light illumination. In contrast, the photocatalytic efficiency was greatly reduced when the reduction temperature increased to 773 K because of the encapsulation of Ag NPs by a thicker TiOx overlay, which significantly weakened visible-light harvesting. Overall, these findings offer an efficient methodology for designing interfacial enhanced plasmonic photocatalysts for the valorization of biomass.

引用

页数：9

共 48 条

[1] Catalytic conversion of solar to chemical energy on plasmonic metal nanostructures [J].

Aslam, Umar ;

Rao, Vishal Govind ;

Chavez, Steven ;

Linic, Suljo .

NATURE CATALYSIS, 2018, 1 (09) :656-665

[2]

Aslam U, 2017, NAT NANOTECHNOL, V12, P1000, DOI [10.1038/nnano.2017.131, 10.1038/NNANO.2017.131]

[3] Photocatalytic Partial Oxidation of 5-Hydroxymethylfurfural (HMF) to 2,5-Diformylfuran (DFF) Over a Covalent Triazine Framework in Water [J].

Ayed, Cyrine ;

Huang, Wei ;

Kizilsavas, Goenuel ;

Landfester, Katharina ;

Zhang, Kai A. I. .

CHEMPHOTOCHEM, 2020, 4 (08) :571-576

[4] Visible light-driven simultaneous H2 production by water splitting coupled with selective oxidation of HMF to DFF catalyzed by porous carbon nitride [J].

Battula, Venugopala Rao ;

Jaryal, Arpna ;

Kailasam, Kamalakannan .

JOURNAL OF MATERIALS CHEMISTRY A, 2019, 7 (10) :5643-5649

[5] The dynamics of overlayer formation on catalyst nanoparticles and strong metal-support interaction [J].

Beck, Arik ;

Huang, Xing ;

Artiglia, Luca ;

Zabilskiy, Maxim ;

Wang, Xing ;

Rzepka, Przemyslaw ;

Palagin, Dennis ;

Willinger, Marc-Georg ;

van Bokhoven, Jeroen A. .

NATURE COMMUNICATIONS, 2020, 11 (01)

[6] Atomic and electronic structures of stable linear carbon chains on Ag-nanoparticles [J].

Boukhvalov, D. W. ;

Zhidkov, I. S. ;

Kurmaev, E. Z. ;

Fazio, E. ;

Cholakh, S. O. ;

D'Urso, L. .

CARBON, 2018, 128 :296-301

[7] Giant Defect-Induced Effects on Nanoscale Charge Separation in Semiconductor Photocatalysts [J].

Chen, Ruotian ;

Pang, Shan ;

An, Hongyu ;

Dittrich, Thomas ;

Fan, Fengtao ;

Li, Can .

NANO LETTERS, 2019, 19 (01) :426-432

[8] A metal-free, high nitrogen-doped nanoporous graphitic carbon catalyst for an effective aerobic HMF-to-FDCA conversion [J].

Chi Van Nguyen ;

Liao, Yu-Te ;

Kang, Ting-Cih ;

Chen, Jeffrey E. ;

Yoshikawa, Takuya ;

Nakasaka, Yuta ;

Masuda, Takao ;

Wu, Kevin C. -W. .

GREEN CHEMISTRY, 2016, 18 (22) :5957-5961

[9] On the mechanism of selective oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid over supported Pt and Au catalysts [J].

Davis, Sara E. ;

Zope, Bhushan N. ;

Davis, Robert J. .

GREEN CHEMISTRY, 2012, 14 (01) :143-147

[10] Visible-Light-Driven Selective Oxidation of Biomass-Derived HMF to DFF Coupled with H2 Generation by Noble Metal-Free Zn0.5Cd0.5S/MnO2 Heterostructures [J].

Dhingra, Suman ;

Chhabra, Tripti ;

Krishnan, Venkata ;

Nagaraja, C. M. .

ACS APPLIED ENERGY MATERIALS, 2020, 3 (07) :7138-7148

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