Temperature dependent selective gas sorption of the microporous metal-imidazolate framework [Cu(L)] [H2L=1,4-di(1H-imidazol-4-yl)benzene]

被引:174
作者
Chen, Shui-Sheng [1 ,3 ]
Chen, Min [1 ]
Takamizawa, Satoshi [2 ]
Chen, Man-Sheng [1 ]
Su, Zhi [1 ]
Sun, Wei-Yin [1 ]
机构
[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Sch Chem & Chem Engn,Nanjing Natl Lab Microstruct, Nanjing 210093, Peoples R China
[2] Yokohama City Univ, Grad Sch Nanobiosci, Kanazawa Ku, Kanagawa 2360027, Japan
[3] Fuyang Teachers Coll, Sch Chem & Chem Engn, Fuyang 236041, Peoples R China
基金
中国国家自然科学基金;
关键词
ORGANIC FRAMEWORKS; HYDROGEN STORAGE; CARBON-DIOXIDE; TRIAZOLATE FRAMEWORKS; ADSORPTION PROPERTIES; ZEOLITIC TOPOLOGIES; CRYSTAL-STRUCTURE; BINDING; METHANE; CO2;
D O I
10.1039/c0cc04085a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A highly stable copper(II) microporous framework with cylindrical channels constructed from 1,4-di(1H-imidazol-4-yl)benzene (H2L) and CuCl2 center dot 2H(2)O is composed of Cu(II)-imidazolate tubes interconnected by the 1,4-phenylene group of L2-, and shows temperature dependent selective gas sorption properties.
引用
收藏
页码:752 / 754
页数:3
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