Addition of ammonia, water, and dihydrogen across a single Pd-Pd bond

被引：170

作者：

Fafard, Claudia M.

Adhikari, Debashis

Foxman, Bruce M.

Mindiola, Daniel J.

Ozerov, Oleg V.

机构：

[1] Brandeis Univ, Dept Chem, Waltham, MA 02454 USA

[2] Indiana Univ, Dept Chem, Bloomington, IN 47405 USA

[3] Indiana Univ, Ctr Mol Struct, Bloomington, IN 47405 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 34期

关键词：

D O I：

10.1021/ja0731571

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pincer-supported Pd alkyl complexes (PNP)PdR undergo photochemical conversion to a dimeric (PNP)Pd-Pd(PNP) complex with a single Pd-Pd bond. Dissociation of the dimer into monomeric (PNP)Pd species is kinetically accessible thermally and photochemically. (PNP)Pd-Pd(PNP) reacts with ammonia, water, and dihydrogen by adding the H-X bond of the substrate (X = NH2, OH, H) across the Pd-Pd bond. For ammonia, this represents a rare example of conversion of NH3 to terminal hydride and amide ligands by a bimetallic complex.

引用

页码：10318 / +

页数：3

共 27 条

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