Synthesis of unsaturated polyester resin - effect of anhydride composition

被引：2

作者：

Ahamad, A ^{[1
]}

Lubic, M ^{[1
]}

Mohan, A ^{[1
]}

Safeer, M ^{[1
]}

Thachil, ET ^{[1
]}

机构：

[1] Dept Polymer Sci & Rubber Technol, Kochi 682022, India

来源：

DESIGNED MONOMERS AND POLYMERS | 2001年 / 4卷 / 03期

关键词：

unsaturated polyester resin; phthalic anhydride; maleic anhydride; esterification; propylene glycol;

D O I：

10.1163/156855501750536242

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Unsaturated polyester resin has been synthesized using different proportions of phthalic anhydride and maleic anhydride for the esterification with propylene glycol. Initially, maleic anhydride was allowed to react with propylene glycol for some time before the addition of phthalic anhydride. The condensate obtained was mixed with styrene monomer to obtain at an unsaturated polyester resin formulation. Mechanical properties such as tensile strength, elongation-at-break, tensile modulus, impact strength, water absorption, toughness, and surface hardness were tested after curing the resin in appropriate molds. The results show that most of the properties are maximum at 60-70% of maleic anhydride.

引用

页码：261 / 268

页数：8

共 19 条

[1] *ASTM, 466287 ASTM D
[2] AUDOJEVA GM, 1982, VYSOKOMOL SOEDIN A, V24, P173
[3] AURIA BD, 1988, J POLYM MATER, V25, P125
[4] BATZER H, 1952, MAKROMOL CHEM, V8, P217
[5] Boeing H.V., 1964, UNSATURATED POLYESTE
[6] BRYDSON JA, 1973, PLASTIC MAT
[7] Carothers W.H., 1929, J. Am. Chem. Soc., V51, P2560, DOI DOI 10.1021/JA01383A042
[8] INHIBITION OF UNSATURATED POLYESTERS
CASS, WE
BURNETT, RE
[J]. INDUSTRIAL AND ENGINEERING CHEMISTRY, 1954, 46 (08): : 1619 - 1624
[9] GOODMAN I, 1972, ENCY POLYM SCI TECHN, V11
[10] JALANDER Y, 1988, ENCY POLYM SCI ENG

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