Solvothermal synthesis and crystal'structure of a polymeric network assembled by tetranuclear [Sm4(en)4(μ3-OH)4]8+ clusters and sulfate anions

被引：20

作者：

Jia, DX

Zhang, Y

Dai, J ^{[1
]}

Zhu, QY

Lu, W

Guo, WJ

机构：

[1] Suzhou Univ, Dept Chem & Chem Engn, Suzhou 215006, Peoples R China

[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2005年 / 8卷 / 07期

基金：

中国国家自然科学基金;

关键词：

solvotherml synthesis; structure; samarium; sulfate; ethylenediamine;

D O I：

10.1016/j.inoche.2005.03.024

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel samarium hydroxyl sulfate, [Sm(en)(mu(3)-OH)(mu(3)-SO4)]infinity, was synthiesized by a solvothermal method and the structure of the coordination polymer takes a diamond-like network assembled by tetranuclear cubane-like (Sm-4(en)(4)(mu(3)-OH)(4)](8+) Clusters and eta(3)-SO42- ion bridges. This structure is unfamiliar in lanthanide network, although some coordination polymers of cubane-like [Ln(4)(mu(3)-OH)(4)](8+) clusters have been reported. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：588 / 591

页数：4

共 45 条

[1] Two new diamine templated lanthanum sulfates, La2(H2O)2(C4H12N2)(SO4)4 and La2(H2O)2(C2H10N2)3(SO4)6•4H2O, with 3D and 2D crystal structures [J].