Transannular [4C+3C]-Cycloaddition Reactions of Oxyallyl Cation to Furan

被引：2
|
作者：
Gung, Benjamin W. [1 ]
Conyers, Ryan [1 ]
机构：
[1] Miami Univ, Dept Chem & Biochem, Oxford, OH 45056 USA
来源：
SYNLETT | 2010年 / 18期
关键词：
transannular; cycloaddition; oxyallyl; macrocycle; acyloin reaction; SPONGE CORTICIUM-SIMPLEX; DIELS-ALDER REACTION; STEROIDAL ALKALOIDS; CYCLOADDITION REACTIONS; ACID; CORTISTATINS; ROUTE; ENTRY;
D O I：
10.1055/s-0030-1258993
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
For the first time, successful transannular [4+3]-cycloaddition reactions based on an oxyallyl cation intermediate are reported. The key steps involve the synthesis of the macrocyclic precursor and the transanuular [4C+3C]-cycloaddition step.
引用
收藏
页码：2797 / 2801
页数：5
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