Measurement of Hydrogen Radical Density and Its Impact on Reduction of Copper Oxide in Atmospheric-Pressure Remote Plasma Using H2 and Ar Mixture Gases

被引:44
作者
Inui, Hirotoshi [1 ]
Takeda, Keigo [1 ]
Kondo, Hiroki [1 ]
Ishikawa, Kenji [1 ]
Sekine, Makoto [1 ]
Kano, Hiroyuki [2 ]
Yoshida, Naofumi [3 ]
Hori, Masaru [1 ]
机构
[1] Nagoya Univ, Dept Elect Engn & Comp Sci, Nagoya, Aichi 4648603, Japan
[2] NU Ecoengn Co Ltd, Aichi 4700201, Japan
[3] Fuji Machine Mfg Co Ltd, Aichi 4728686, Japan
关键词
DIELECTRIC BARRIER DISCHARGE; GLOW-DISCHARGE; THIN-FILMS; OXIDATION; PHYSICS;
D O I
10.1143/APEX.3.126101
中图分类号
O59 [应用物理学];
学科分类号
摘要
A 60 Hz alternating current excited atmospheric-pressure plasma with an ultrahigh electron density of over 10(16) cm(-3) employing H-2/Ar [p(H-2)/p(H-2 + Ar) 1-3%] gases was used to reduce copper oxides on copper. The remote plasma reduced CuO and Cu2O at room temperature. The ground-state hydrogen (H) radical density in the atmospheric-pressure plasma was measured by vacuum ultraviolet absorption spectroscopy using a micro hollow cathode lamp. The ratio of reduction of amount of CuO flux to the H radical flux was determined from the measured H radical density and gas temperature. (C) 2010 The Japan Society of Applied Physics
引用
收藏
页数:3
相关论文
共 17 条
[1]  
[Anonymous], PLASMA SPECTROSCOPY
[2]   CARS diagnostic and modeling of a dielectric barrier discharge [J].
Baeva, M ;
Dogan, A ;
Ehlbeck, J ;
Pott, A ;
Uhlenbusch, J .
PLASMA CHEMISTRY AND PLASMA PROCESSING, 1999, 19 (04) :445-466
[3]   ESCA STUDIES OF NATURALLY PASSIVATED METAL FOILS [J].
BARR, TL .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY, 1977, 14 (01) :660-665
[4]   Oxidation study of pure tin and its alloys via electrochemical reduction analysis [J].
Cho, S ;
Yu, J ;
Kang, SK ;
Shih, DY .
JOURNAL OF ELECTRONIC MATERIALS, 2005, 34 (05) :635-642
[5]   STARK PROFILE CALCULATIONS FOR H-BETA LINE OF HYDROGEN [J].
GRIEM, HR ;
SHEN, KY ;
KOLB, AC .
ASTROPHYSICAL JOURNAL, 1962, 135 (01) :272-&
[6]   Nonequilibrium atmospheric pressure plasma with ultrahigh electron density and high performance for glass surface cleaning [J].
Iwasaki, Masahiro ;
Inui, Hirotoshi ;
Matsudaira, Yuto ;
Kano, Hiroyuki ;
Yoshida, Naofumi ;
Ito, Masafumi ;
Hori, Masaru .
APPLIED PHYSICS LETTERS, 2008, 92 (08)
[7]   STABLE GLOW PLASMA AT ATMOSPHERIC-PRESSURE [J].
KANAZAWA, S ;
KOGOMA, M ;
MORIWAKI, T ;
OKAZAKI, S .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 1988, 21 (05) :838-840
[8]   Reduction of CuO and Cu2O with H2:H embedding and kinetic effects in the formation of suboxides [J].
Kim, JY ;
Rodriguez, JA ;
Hanson, JC ;
Frenkel, AI ;
Lee, PL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (35) :10684-10692
[9]   Dielectric-barrier discharges: Their history, discharge physics, and industrial applications [J].
Kogelschatz, U .
PLASMA CHEMISTRY AND PLASMA PROCESSING, 2003, 23 (01) :1-46
[10]   Physics and chemistry in a glow dielectric barrier discharge at atmospheric pressure:: diagnostics and modelling [J].
Massines, F ;
Ségur, P ;
Gherardi, N ;
Khamphan, C ;
Ricard, A .
SURFACE & COATINGS TECHNOLOGY, 2003, 174 :8-14