MnCl2•4H2O-catalyzed Potential Protocol for the Synthesis of Aryl/Vinyl Sulfides

被引:24
作者
Bandaru, Madhav [1 ]
Sabbavarpu, Narayana Murthy [1 ]
Katla, Ramesh [1 ]
Yadavalli, Venkata Durga Nageswar [1 ]
机构
[1] Indian Inst Chem Technol, Organ Chem Div 1, Hyderabad 500607, Andhra Pradesh, India
关键词
CROSS-COUPLING REACTIONS; LIGAND-FREE CONDITIONS; SULFUR BOND FORMATION; VINYL SULFIDES; ARYL HALIDES; STEREOSELECTIVE-SYNTHESIS; C-C; PALLADIUM CATALYSTS; GRIGNARD-REAGENTS; THIOLS;
D O I
10.1246/cl.2010.1149
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
MnCl2 4H(2)O is described as an efficient catalytic system for the cross coupling of aryl/vinyl halides with thiols using KOH as base and DMSO as solvent By using this new catalytic system various aryl/vinyl sulfides were synthesized in moderate to good yields Retention of stereochemistry is observed in the case of vinyl sulfides
引用
收藏
页码:1149 / 1151
页数:3
相关论文
共 78 条
[1]  
Alami M, 1998, SYNLETT, P325
[2]  
[Anonymous], J ORG CHEM
[3]   Effect of substitution of [Pd(PPh3)4] by related compounds as catalysts in reactions of organic syntheses [J].
Barbieri, Roberto S. ;
Bellato, C. R. ;
Dias, A. K. C. ;
Massabni, A. C. .
CATALYSIS LETTERS, 2006, 109 (3-4) :171-174
[4]   Catechol violet as new, efficient, and versatile ligand for Cu(I)-catalyzed C-S coupling reactions [J].
Basu, Basudeb ;
Mandal, Bablee ;
Das, Sajal ;
Kundu, Sekhar .
TETRAHEDRON LETTERS, 2009, 50 (39) :5523-5528
[5]   Copper-catalyzed synthesis of vinyl sulfides [J].
Bates, CG ;
Saejueng, P ;
Doherty, MQ ;
Venkataraman, D .
ORGANIC LETTERS, 2004, 6 (26) :5005-5008
[6]   A general method for the formation of aryl-sulfur bonds using copper(I) catalysts [J].
Bates, CG ;
Gujadhur, RK ;
Venkataraman, D .
ORGANIC LETTERS, 2002, 4 (16) :2803-2806
[7]   MANGANESE(II) CATALYSIS .1. COUPLING REACTION OF IODOALKENES TO DIENES BY ORGANOLITHIUM REAGENTS IN PRESENCE OF MANGANESE(II) [J].
CAHIEZ, G ;
BERNARD, D ;
NORMANT, JF .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1976, 113 (02) :99-106
[8]   Unexpected cross-coupling reaction between o-chloroaryl ketones and organomanganese reagents [J].
Cahiez, G ;
Luart, D ;
Lecomte, F .
ORGANIC LETTERS, 2004, 6 (24) :4395-4398
[9]  
Cahiez G, 1999, SYNTHESIS-STUTTGART, P2138
[10]   Rapid palladium-catalyzed cross-coupling in the synthesis of aryl thioethers under microwave conditions [J].
Cai, Lisheng ;
Cuevas, Jessica ;
Peng, Yi-Yuan ;
Pike, Victor W. .
TETRAHEDRON LETTERS, 2006, 47 (26) :4449-4452