Synthesis of Well-Defined Polymers via Mechanism Transformation Between Living Ring-Opening Polymerization and Controlled Free Radical Polymerization

被引：0

作者：

Zhou Lilin ^{[1
]}

Yuan Jinying ^{[1
]}

Cai Zhinan ^{[1
]}

Hong Xiaoyin ^{[1
]}

机构：

[1] Tsinghua Univ, Dept Chem, Key Lab Organ Optoelect & Mol Engn, Minist Educ, Beijing 100084, Peoples R China

来源：

PROGRESS IN CHEMISTRY | 2010年 / 22卷 / 09期

关键词：

living ring-opening polymerization; controlled free radical polymerization; mechanism transformation; ATRP; RAFT; SFRP; STAR-BLOCK-COPOLYMERS; FRAGMENTATION CHAIN-TRANSFER; SEQUENTIAL CONTROLLED POLYMERIZATION; AMPHIPHILIC DIBLOCK COPOLYMERS; CLICK CHEMISTRY; SHAPED COPOLYMERS; VERSATILE APPROACH; GRAFT-COPOLYMERS; ENZYMATIC ROP; SIDE-CHAINS;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Controlled radical polymerization and living ring-opening polymerization can be combined by mechanism transformation to synthesize various copolymers with novel well-defined macromolecular architectures. This method has received much attention. This article summarizes recent research progress on the preparation of well-defined copolymers by mechanism transformation between controlled radical polymerizations, including atom transfer radical polymerization (ATRP), reversible addition-fragmentation transfer (RAFT) polymerization, and stable free-radical polymerization (SFRP), with living ring-opening polymerization(ROP).

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页码：1799 / 1807

页数：9

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