High efficiency solid-state sensitized heterojunction photovoltaic device

被引:65
作者
Wang, Mingkui [2 ]
Liu, Jingyuan [1 ]
Cevey-Ha, Ngoc-Le [2 ]
Moon, Soo-Jin [2 ]
Liska, Paul [2 ]
Humphry-Baker, Robin [2 ]
Moser, Jacques-E. [2 ]
Graetzel, Carole [2 ]
Wang, Peng [1 ]
Zakeeruddin, Shaik M. [2 ]
Graetzel, Michael [2 ]
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
[2] Ecole Polytech Fed Lausanne, Inst Chem Sci & Engn, LPI, CH-1015 Lausanne, Switzerland
基金
瑞士国家科学基金会;
关键词
Solar cell; Sensitizer; Photoinduced absorption spectroscopy; Photovoltage transient spectroscopy; Charge recombination; PHOTOINDUCED ABSORPTION-SPECTROSCOPY; SOLAR-CELLS; ELECTRON-TRANSPORT; CHARGE-TRANSPORT; SPIRO-OMETAD; DYE; RECOMBINATION; PERFORMANCE; FILM; TOOL;
D O I
10.1016/j.nantod.2010.04.001
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The high molar extinction coefficient heteroleptic ruthenium dye, NaRu(4,4'-bis(5-(hexylthio)thiophen-2-yl)-2,2'-bipyridine) (4-carboxylic acid-4'-carboxylate-2,2'-bipyridine) (NCS)(z), exhibits certified 5% electric power conversion efficiency at AM 1.5 solar irradiation (100 mWcm(-2)) in a solid-state dye-sensitized solar cell using 2,2',7,7'-tetrakis-(N,N-dipmethoxyphenylamine)-9,9'-spirobifluorene (spiro-MeOTAD) as the organic hole-transporting material. This demonstration elucidates a class of photovoltaic devices with potential for low-cost power generation. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码:169 / 174
页数:6
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