New Cyano-Group-Containing 1,3-Oxaselenoles: Nucleophilic Substitution of a Cyano Group with Rearrangement

被引：1
|
作者：
Kachanov, Andrey V. [1 ]
Zamaraev, Andrey V. [2 ]
Gerasimenko, Andrey V. [3 ]
Maslov, Konstantin V. [1 ]
Slabko, Oleg Yu. [1 ]
Kaminskii, Vladimir A. [1 ]
机构：
[1] Far Eastern Fed Univ, Sch Nat Sci, Sukhanov Str 8, Vladivostok 690950, Russia
[2] Russian Acad Sci, Far East Branch, GB Elyakov Pacific Inst Bioorgan Chem, Prospect 100 Let Vladivostoku 159, Vladivostok 690022, Russia
[3] Russian Acad Sci, Far East Branch, Inst Chem, Prospect 100 Let Vladivostoku 159, Vladivostok 690022, Russia
来源：
SYNLETT | 2018年 / 29卷 / 15期
关键词：
aroylacetonitriles; selenium oxide; oxaselenoles; nucleophilic substitution; rearrangement; SELENIUM DIOXIDE; MALONONITRILE; DERIVATIVES; OXIDATION; YLIDES; ROUTE;
D O I：
10.1055/s-0037-1609939
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
New cyano-group-containing 1,3-oxaselenoles were obtained by the treatment of aroylacetonitriles with selenium(IV) oxide. The resulting products were shown to react with ammonia, hydrazine, or primary amines; this reaction was accompanied by aryl rearrangement.
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收藏
页码：2035 / 2038
页数：4
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