Thermo-to-photo-switching of the chromic behavior of salicylideneanilines by inclusion in a porous coordination network

被引：100

作者：

Haneda, Tsuyoshi

Kawano, Masaki ^{[1
]}

Kojima, Takahiro

Fujita, Makoto

机构：

[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Tokyo 1138656, Japan

[2] Genesis Res Inst Inc, Tokyo 1138656, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 35期

关键词：

coordination networks; host-guest systems; photochromism; structure elucidation; thermochromism;

D O I：

10.1002/anie.200700999

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Insert and twist: By inclusion in the channel of a porous coordination network, an otherwise thermochromic salicylideneaniline derivative becomes photochromic because its intrinsic planar conformation is transformed into a nonplanar one. The photochromic properties of the nonplanar guest molecule can be tuned by changing the co-included solvent in the channel. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：6643 / 6645

页数：3

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