Molecularly defined palladium(0) monophosphine complexes as catalysts for efficient cross-coupling of aryl chlorides and phenylboronic acid

被引：143

作者：

Andreu, MG ^{[1
]}

Zapf, A ^{[1
]}

Beller, M ^{[1
]}

机构：

[1] Univ Rostock, Inst Organ Katalyseforsch, D-18055 Rostock, Germany

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 24期

关键词：

D O I：

10.1039/b006791l

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Various 1,6-diene palladium(0) monophosphine complexes have been prepared from tmedaPd(CH3)(2), PR3, and the corresponding 1,6-diene. These molecularly defined Pd complexes catalyzed the Suzuki coupling of aryl chlorides with phenylboronic acid more efficiently than traditional Pd-II-PR3 pre-catalysts.

引用

页码：2475 / 2476

页数：2

共 39 条

[1] Anionic Pd(0) and Pd(II) intermediates in palladium-catalyzed Heck and cross-coupling reactions
Amatore, C
Jutand, A
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2000, 33 (05) : 314 - 321
[2] [Anonymous], ANGEW CHEM
[3] A convenient palladium/ligand catalyst for Suzuki cross-coupling reactions of arylboronic acids and aryl chlorides
Bei, XH
Crevier, T
Guram, AS
Jandeleit, B
Powers, TS
Turner, HW
Uno, T
Weinberg, WH
[J]. TETRAHEDRON LETTERS, 1999, 40 (20) : 3855 - 3858
[4] Beller M., 1995, ANGEW CHEM, V107, P1992
[5] N-heterocyclic carbenes Part 26.: N-heterocyclic carbene complexes of palladium(0):: synthesis and application in the Suzuki cross-coupling reaction
Böhm, VPW
Gstöttmayr, CWK
Weskamp, T
Herrmann, WA
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 595 (02) : 186 - 190
[6] EHRENTRAUT A, IN PRESS SYNLETT
[7] GEISSLER H, 1998, TRANSITION METALS OR, V1
[8] Gröger H, 2000, J PRAK CHEM-CHEM ZTG, V342, P334
[9] TRANSFORMATIONS OF CHLOROARENES, CATALYZED BY TRANSITION-METAL COMPLEXES
GRUSHIN, VV
ALPER, H
[J]. CHEMICAL REVIEWS, 1994, 94 (04) : 1047 - 1062
[10] OXIDATIVE ADDITION OF ARYL BROMIDE AFTER DISSOCIATION OF PHOSPHINE FROM A 2-COORDINATE PALLADIUM(0) COMPLEX, BIS(TRI-O-TOLYLPHOSPHINE)PALLADIUM(0)
HARTWIG, JF
PAUL, F
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (19) : 5373 - 5374

← 1 2 3 4 →