(OC-6-33)-(2,2'-Bipyridine-κ2 N,N')trimethyl(2-methylsulfanyl-2-thiazoline-κN)platinum(IV) tetrafluoridoborate

被引：2

作者：

Vetter, Cornelia ^{[1
]}

Bruhn, Clemens ^{[2
]}

Steinborn, Dirk ^{[1
]}

机构：

[1] Univ Halle Wittenberg, Inst Chem Anorgan Chem, D-06120 Halle, Germany

[2] Univ Kassel, Inst Chem, D-34132 Kassel, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷

关键词：

PLATINUM(IV); COMPLEXES;

D O I：

10.1107/S1600536810027546

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The asymmetric unit of the title complex, [Pt(CH3)(3)(C10H8N2)(C4H7NS2)]BF4, contains two crystallographically independent molecules. The PtIV atom in each complex cation exhibits a distorted octahedral coordination geometry, built up by three methyl ligands in a facial binding fashion, a bipyridine ligand and a monodentately N-bound 2-methylsulfanyl-2-thiazoline ligand (configuration index: OC-6-33). In the crystal structure, weak intermolecular C-H...F hydrogen bonds are found between the complex cations and BF4 - anions.

引用

页码：M941 / U787

页数：14

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