Porous metal-organic frameworks as platforms for functional applications

被引：830
作者：
Jiang, Hai-Long [1 ]
Xu, Qiang [1 ]
机构：
[1] Natl Inst Adv Ind Sci & Technol, Osaka 5638577, Japan
来源：
CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 12期
关键词：
MICROPOROUS COORDINATION POLYMERS; GAS-CHROMATOGRAPHIC SEPARATION; ENHANCED HYDROGEN STORAGE; MOLECULAR-SIEVE MEMBRANE; LIQUID-PHASE ADSORPTION; CUBIC BUILDING-BLOCKS; XYLENE ISOMERS; GOLD CLUSTERS; SELECTIVE ADSORPTION; IMIDAZOLATE FRAMEWORKS;
D O I：
10.1039/c0cc05419d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Metal-organic frameworks (MOFs), also known as coordination polymers, have emerged as a new class of crystalline porous materials, which are constructed from metal ions or metal ion clusters and bridging organic linkers. MOFs have tunable pores and functionalities, and usually exhibit very high surface areas. The potential applications of porous MOFs cover a broad range of fields and most of their applications are related to pore sizes, shapes and structures/environments. In this feature article, we provide an overview of the recent developments of porous MOFs as platforms in the functional applications of sorption and separation, heterogeneous catalysis, as supports/host matrices for metal nanoparticles, and as templates/nanoreactors for new material preparation.
引用
收藏
页码：3351 / 3370
页数：20
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