Nitrile-Rich Coordination Polymer ∞1{[Fe(CH3CN)4(pyrazine)](CIO4)2} Exhibiting a HS ⇆ LS Transition

被引：16

作者：

Bialonska, Agata ^{[1
]}

Bronisz, Robert ^{[1
]}

Darowska, Kamilla ^{[1
]}

Drabent, Krzysztof ^{[1
]}

Kusz, Joachim ^{[2
]}

Siczek, Milosz ^{[1
]}

Weselski, Marek ^{[1
]}

Zubko, Maciej ^{[2
]}

Ozarowski, Andrew ^{[3
]}

机构：

[1] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland

[2] Univ Silesia, Inst Phys, PL-40007 Katowice, Poland

[3] Florida State Univ, Natl High Magnet Field Lab, Tallahassee, FL 32310 USA

来源：

INORGANIC CHEMISTRY | 2010年 / 49卷 / 24期

关键词：

SPIN-CROSSOVER COMPLEXES; FAMILY; STATE;

D O I：

10.1021/ic102040y

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In a 1D network of (1)(infinity){[Fe(CH3CN)(4)(pyrazine)}(CIO4)(2)], the presence of four neutral nitrile molecules besides the pyrazine donors in the first coordination sphere of iron(II) allows one to achieve a ligand field strength appropriate for the "spin-crossover" occurrence.

引用

收藏

页码：11267 / 11269

页数：3

相关论文

共 22 条

[1] Oxidative Addition of Halogens on Open Metal Sites in a Microporous Spin-Crossover Coordination Polymer [J].

Agusti, Gloria ;

Ohtani, Ryo ;

Yoneda, Ko ;

Gaspar, Ana B. ;

Ohba, Masaaki ;

Sanchez-Royo, Juan F. ;

Carmen Munoz, M. ;

Kitagawa, Susumu ;

Real, Jose A. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (47) :8944-8947

[2] Designing dinuclear iron(II) spin crossover complexes. Structure and magnetism of dinitrile-, dicyanamido-, tricyanomethanide-, bipyrimidine- and tetrazine-bridged compounds [J].

Batten, SR ;

Bjernemose, J ;

Jensen, P ;

Leita, BA ;

Murray, KS ;

Moubaraki, B ;

Smitha, JP ;

Toftlund, H .

DALTON TRANSACTIONS, 2004, (20) :3370-3375

[3] Oxidation of the pyrazine(pyz)-bridged polymeric copper(I) cation [Cu(cnge)(MeCN)(pyz)](+) by NOBF4 and formation of the corresponding copper(II) cation [Cu(MeCN)(4)(pyz)](2)+ (cnge=2-cyanoguanidine) [J].

Begley, MJ ;

Hubberstey, P ;

Stroud, J .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (11) :2323-2328

[4] A new family of spin-crossover complexes based on a FeII(tetrazolyl)4(MeCN)2-type core [J].

Bialonska, Agata ;

Bronisz, Robert ;

Weselski, Marek .

INORGANIC CHEMISTRY, 2008, 47 (11) :4436-4438

[5] High Spin and Spin-Crossover Two-Dimensional Coordination Polymers Containing FeII(tetrazol-2-yl)4(solv)2 (solv = Ethanol, Acetonitrile) Cores Linked by Flexible/Elastic Spacers [J].

Bialonska, Agata ;

Bronisz, Robert .

INORGANIC CHEMISTRY, 2010, 49 (10) :4534-4542

[6] Spin-crossover nanocrystals with magnetic, optical, and structural bistability near room temperature [J].

Boldog, Ishtvan ;

Gaspar, Ana B. ;

Martinez, Victor ;

Pardo-Ibanez, Pablo ;

Ksenofontov, Vadim ;

Bhattacharjee, Ashis ;

Guetlich, Philipp ;

Real, Jose A. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (34) :6433-6437

[7] Photoswitching of the dielectric constant of the spin-crossover complex [Fe(L)(CN)2]•H2O [J].

Bonhommeau, S ;

Guillon, T ;

Daku, LML ;

Demont, P ;

Costa, JS ;

Létard, JF ;

Molnár, G ;

Bousseksou, A .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (10) :1625-1629

[8] One shot laser pulse induced reversible spin transition in the spin-crossover complex [Fe(C4H4N2]{Pt(CN)4}] at room temperature [J].

Bonhommeau, S ;

Molnár, G ;

Galet, A ;

Zwick, A ;

Real, JA ;

McGarvey, JJ ;

Bousseksou, A .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (26) :4069-4073

[9] Multilayer sequential assembly of thin films that display room-temperature spin crossover with hysteresis [J].

Cobo, Saioa ;

Molnar, Gabor ;

Real, Jose Antonio ;

Bousseksou, Azzedine .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (35) :5786-5789

[10] Ligand design in coordination chemistry: approaches to new catalysts, new materials, and a more sustainable environment [J].

Elsevier, CJ ;

Reedijk, J ;

Walton, PH ;

Ward, MD .

DALTON TRANSACTIONS, 2003, (10) :1869-1880