Bright UV Single Photon Emission at Point Defects in h-BN

被引:382
作者
Bourrellier, Romain [1 ]
Meuret, Sophie [1 ]
Tararan, Anna [1 ]
Stephan, Odile [1 ]
Kociak, Mathieu [1 ]
Tizei, Luiz H. G. [1 ]
Zobelli, Alberto [1 ]
机构
[1] Univ Paris Sud, CNRS, UMR 8502, Lab Phys Solides, F-91405 Orsay, France
关键词
Boron nitride; point defects; single photon source; ultraviolet; cathodoluminescence; scanning transmission electron microscopy; HEXAGONAL BORON-NITRIDE; ATOMICALLY THIN SEMICONDUCTOR; ROOM-TEMPERATURE; LUMINESCENCE; DIAMOND; EMITTERS; FILMS; WSE2;
D O I
10.1021/acs.nanolett.6b01368
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
To date, quantum sources in the ultraviolet (UV) spectral region have been obtained only in semiconductor quantum dots. Color centers in wide bandgap materials may represent a more effective alternative. However, the quest for UV quantum emitters in bulk crystals faces the difficulty of combining an efficient UV excitation/detection optical setup with the capability of addressing individual color centers in potentially highly defective materials. In this work we overcome this limit by employing an original experimental setup coupling cathodoluminescence within a scanning transmission electron microscope to a Hanbury-Brown-Twiss intensity interferometer. We identify a new extremely bright UV single photon emitter (4.1 eV) in hexagonal boron nitride. Hyperspectral cathodoluminescence maps show a high spatial localization of the emission (similar to 80 nm) and a typical zero phonon line plus phonon replica spectroscopic signature, indicating a point defect origin, most likely carbon substitutional at nitrogen sites. An additional nonsingle-photon broad emission may appear in the same spectral region, which can be attributed to intrinsic defects related to electron irradiation.
引用
收藏
页码:4317 / 4321
页数:5
相关论文
共 49 条
[1]   Coupling of excitons and defect states in boron-nitride nanostructures [J].
Attaccalite, C. ;
Bockstedte, M. ;
Marini, A. ;
Rubio, A. ;
Wirtz, L. .
PHYSICAL REVIEW B, 2011, 83 (14)
[2]   Nanometric Resolved Luminescence in h-BN Flakes: Excitons and Stacking Order [J].
Bourrellier, Romain ;
Amato, Michele ;
Tizei, Luiz Henrique Galvao ;
Giorgetti, Christine ;
Gloter, Alexandre ;
Heggie, Malcolm I. ;
March, Katia ;
Stephan, Odile ;
Reining, Lucia ;
Kociak, Mathieu ;
Zobelli, Alberto .
ACS PHOTONICS, 2014, 1 (09) :857-862
[3]   Photon antibunching in the fluorescence of individual color centers in diamond [J].
Brouri, R ;
Beveratos, A ;
Poizat, JP ;
Grangier, P .
OPTICS LETTERS, 2000, 25 (17) :1294-1296
[4]  
BROWN RH, 1956, NATURE, V178, P1046
[5]   Practical free-space quantum key distribution over 1 km [J].
Buttler, WT ;
Hughes, RJ ;
Kwiat, PG ;
Lamoreaux, SK ;
Luther, GG ;
Morgan, GL ;
Nordholt, JE ;
Peterson, CG ;
Simmons, CM .
PHYSICAL REVIEW LETTERS, 1998, 81 (15) :3283-3286
[6]   Hexagonal boron nitride is an indirect bandgap semiconductor [J].
Cassabois, G. ;
Valvin, P. ;
Gil, B. .
NATURE PHOTONICS, 2016, 10 (04) :262-+
[7]   Intervalley scattering in hexagonal boron nitride [J].
Cassabois, G. ;
Valvin, P. ;
Gil, B. .
PHYSICAL REVIEW B, 2016, 93 (03)
[8]  
Castelletto S, 2014, NAT MATER, V13, P151, DOI [10.1038/nmat3806, 10.1038/NMAT3806]
[9]   Room Temperature Quantum Emission from Cubic Silicon Carbide Nanoparticles [J].
Castelletto, Stefania ;
Johnson, Brett C. ;
Zachreson, Cameron ;
Beke, David ;
Balogh, Istvan ;
Ohshima, Takeshi ;
Aharonovich, Igor ;
Gali, Adam .
ACS NANO, 2014, 8 (08) :7938-7947
[10]  
Chakraborty C, 2015, NAT NANOTECHNOL, V10, P507, DOI [10.1038/nnano.2015.79, 10.1038/NNANO.2015.79]