Gas-driven hydrogen permeation in the surface-limited regime

Gas-driven permeation of hydrogen through metal membranes in the surface-limited regime (SLR) is analyzed. An analytical solution for the concentration and permeation flux as a function of time is given for permeation through the asymmetric membrane having different conditions on the inlet and outlet sides. The features of the steady state and transient permeation are discussed. Comparison of calculations with an experiment on deuterium permeation through vanadium, which is available from literature, is performed. It has been demonstrated that the parameters, extracted from the measurements of the permeation rate in SLR are very uncertain. Even the calculations with opposite asymmetries can be equally well adjusted to the experiment. Non-zero initial conditions in SLR experiments are additional source of uncertainty. Measurements of the accumulation in a closed volume instead of the permeation rate can seriously mislead in the interpretation of the experiment. Complementary experiments on permeation in two opposite directions and measurements of permeation decay could increase the reliability of the data obtained. (C) 2003 Elsevier B.V. All rights reserved.