A bifunctionalized porous material containing discrete assemblies of copper-porphyrins and calixarenes metallated by ion diffusion

被引：12

作者：

De Zorzi, Rita ^{[1
]}

Guidolin, Nicol ^{[1
]}

Randaccio, Lucio ^{[1
]}

Geremia, Silvano ^{[1
]}

机构：

[1] Univ Trieste, Dept Chem Sci, Ctr Excellence Biocrystallog, I-34127 Trieste, Italy

来源：

CRYSTENGCOMM | 2010年 / 12卷 / 12期

关键词：

NONCOVALENT SYNTHESIS; AQUEOUS-SOLUTION; COORDINATION; COMPLEXES; STOICHIOMETRY; ARRAYS; ENERGY;

D O I：

10.1039/c0ce00440e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Nanoporous crystals of discrete stacks of metallo-porphyrins together with exogenous metal centers have been obtained by synergistic non-covalent interactions of tetra-cationic copper(II)-meso-tetrakis(4-N-methylpyridyl)porphyrin and polyanionic tetrasulfonato-tetrakis(hydroxylcarbonylmethoxy)calix[4]arene building blocks successively functionalized by diffusion and coordination of Zn2+ or Ni2+ ions.

引用

页码：4056 / 4058

页数：3

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