A facile and efficient deoxygenation of amine-N-oxides with Mo(CO)6

被引:36
|
作者
Yoo, BW [1 ]
Choi, JW [1 ]
Yoon, CM [1 ]
机构
[1] Korea Univ, Dept Adv Mat Chem, Jochiwon 339700, Chungnam, South Korea
关键词
deoxygenation; amine-N-oxides; amine; Mo(CO)6 center dot;
D O I
10.1016/j.tetlet.2005.10.143
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A variety of amine-N-oxides have been found to be selectively deoxygenated to the corresponding amines in high yields with Mo(CO)(6) in ethanol under mild conditions. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:125 / 126
页数:2
相关论文
共 50 条
  • [21] Facile and efficient deoxygenation of aromatic N-oxides with zinc and aqueous ammonium chloride
    Aoyagi, Y
    Abe, T
    Ohta, A
    SYNTHESIS-STUTTGART, 1997, (08): : 891 - &
  • [22] Mo(CO)6-promoted facile deoxygenation of α,β-epoxy ketones and α,β-epoxy esters
    Patra, A
    Bandyopadhyay, M
    Mal, D
    TETRAHEDRON LETTERS, 2003, 44 (11) : 2355 - 2357
  • [23] An Improved Rapid and Mild Deoxygenation of Amine N-oxides
    Rajesh, Y. B. R. D.
    JOURNAL OF HETEROCYCLIC CHEMISTRY, 2018, 55 (02) : 486 - 491
  • [24] Oxygen Atom Transfer to Cationic PCPNi(II) Complexes Using Amine-N-Oxides
    LaPierre, Etienne A.
    Clapson, Marissa L.
    Piers, Warren E.
    Maron, Laurent
    Spasyuk, Denis M.
    Gendy, Chris
    INORGANIC CHEMISTRY, 2018, 57 (01) : 495 - 506
  • [25] REACTIONS CONCERNED IN TERTIARY AMINE-N-OXIDES .2. REACTIONS OF PYRIDINE AND QUINOLINE SERIES WITH THEIR N-OXIDES
    HAGINIWA, J
    HIGUCHI, Y
    YAKUGAKU ZASSHI-JOURNAL OF THE PHARMACEUTICAL SOCIETY OF JAPAN, 1973, 93 (02): : 144 - 148
  • [26] An efficient deoxygenation of nitrones and heteroarene N-oxides
    Dutta, DK
    Konwar, D
    JOURNAL OF CHEMICAL RESEARCH-S, 1998, (05): : 266 - +
  • [27] Copper-catalyzed oxygen atom transfer of N-oxides leading to a facile deoxygenation procedure applicable to both heterocyclic and amine N-oxides
    Jeong, Jisu
    Lee, Donggun
    Chang, Sukbok
    CHEMICAL COMMUNICATIONS, 2015, 51 (32) : 7035 - 7038
  • [28] REDUCTION BY SULFOXIDES - MECHANISM OF DEOXYGENATION OF HETEROCYCLIC N-OXIDES AND TERTIARY AMINE N-OXIDES
    BIFFIN, MEC
    BOCKSTEI.G
    MILLER, J
    PAUL, DB
    AUSTRALIAN JOURNAL OF CHEMISTRY, 1974, 27 (04) : 789 - 799
  • [29] Amphiphilic amine-N-oxides with aliphatic alkyl chain act as efficient superoxide dismutase mimics, antioxidants and lipid peroxidation blockers in yeast
    A. Krasowska
    A. Piasecki
    A. Polinceusz
    A. Prescha
    K. Sigler
    Folia Microbiologica, 2006, 51 : 99 - 107
  • [30] Amphiphilic amine-N-oxides with aliphatic alkyl chain act as efficient superoxide dismutase mimics, antioxidants and lipid peroxidation blockers in yeast
    Krasowska, A.
    Piasecki, A.
    Polinceusz, A.
    Prescha, A.
    Sigler, K.
    FOLIA MICROBIOLOGICA, 2006, 51 (02) : 99 - 107