Formation of C-C bonds via ruthenium-catalyzed transfer hydrogenation

被引:98
作者
Moran, Joseph [1 ]
Krische, Michael J. [1 ]
机构
[1] Univ Texas Austin, Dept Chem & Biochem, 1 Univ Stn A5300, Austin, TX 78712 USA
基金
加拿大自然科学与工程研究理事会;
关键词
C-C bond formation; catalysis; ruthenium catalysis; transfer hydrogenation; ALDEHYDE OXIDATION LEVEL; TRISUBSTITUTED ALLYLIC ALCOHOLS; FORMING TRANSFER HYDROGENATION; CARBONYL ALLYLATION; INTERMOLECULAR HYDROACYLATION; REDUCTIVE CYCLIZATION; REVERSE PRENYLATION; CONJUGATED ALKYNES; PI-ALLYLPALLADIUM; METAL REAGENTS;
D O I
10.1351/PAC-CON-11-10-18
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ruthenium-catalyzed transfer hydrogenation of diverse p-unsaturated reactants in the presence of aldehydes provides products of carbonyl addition. Dehydrogenation of primary alcohols in the presence of the same p-unsaturated reactants provides identical products of carbonyl addition. In this way, carbonyl addition is achieved from the alcohol or aldehyde oxidation level in the absence of stoichiometric organometallic reagents or metallic reductants. In this account, the discovery of ruthenium-catalyzed C-C bond-forming transfer hydrogenations and the recent development of diastereo- and enantioselective variants are discussed.
引用
收藏
页码:1729 / 1739
页数:11
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