Ligand Mediated Morphology of the Two-Dimensional Uranyl Aqua Sulfates [UO2(X)(SO4)(H2O)] [X = Cl- or (CH3)3NCH2COO]

被引：6
作者：
Smith, Philip A. [1 ]
Burns, Peter C. [1 ]
机构：
[1] Univ Notre Dame, Dept Civil & Environm Engn & Earth Sci, Notre Dame, IN 46556 USA
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2019年 / 645卷 / 05期
关键词：
Uranyl; Betaine; Halide; Ionic liquid; Betainium; Uranium; Coordination; HIERARCHY;
D O I：
10.1002/zaac.201800320
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two uranyl aqua sulfate compounds: [(CH3)(3)NCH2COOH] [UO2(Cl)(SO4)(H2O)] (1) and UO2((CH3)(3)NCH2COO)(SO4)(H2O) (2) were synthesized and their crystal structures were determined. The morphology changes between the two-dimensional anionic structural unit of 1 and the neutral structural unit of 2 are examined, and the impact of their terminally coordinating ligands discussed.
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页码：504 / 508
页数：5
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