Dithiocarbamate ligand stabilised gold nanoparticles

被引：106
作者：
Vickers, MS
Cookson, J
Beer, PD
Bishop, PT
Thiebaut, B
机构：
[1] Univ Oxford, Dept Chem, Inorgan Chem Lab, Oxford OX1 3QR, England
[2] Johnson Matthey Technol Ctr, Reading RG4 9NH, Berks, England
来源：
JOURNAL OF MATERIALS CHEMISTRY | 2006年 / 16卷 / 02期
关键词：
D O I：
10.1039/b509173j
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Dithiocarbamates are used as adsorbates for the preparation of gold nanoparticles. A range of mono- and tetrakis-functionalised dithiocarbamate ligands containing alkyl, benzyl and resorcinarene cavitand substituents are synthesised. Nanoparticles are prepared by a two-phase synthesis and are characterised by H-1 NMR spectroscopy, UV-Visible spectroscopy, transmission electron microscopy (TEM), energy dispersive X-ray analysis (EDX) and elemental analysis. The colloids are found to be stable over a number of months storage in air. The synthetic versatility of the dithiocarbamate ligand is further demonstrated by the synthesis of ruthenium(II) bipyridyl dithiocarbamate capped gold nanoparticles.
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收藏
页码：209 / 215
页数：7
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