Valorisation of phosphogypsum as building material: radiological aspects

被引:9
作者
Tayibi, H. [1 ]
Gasco, C. [2 ]
Navarro, N. [2 ]
Lopez-Delgado, A. [1 ]
Alvarez, A. [2 ]
Yaguee, L. [2 ]
Alguacil, F. J. [1 ]
Lopez, F. A. [1 ]
机构
[1] Ctr Nacl Invest Met CSIC, Madrid, Spain
[2] Ctr Invest Energet Medioambient & Tecnol CIEMAT, Madrid, Spain
关键词
phosphogypsum; natural radioactivity; TENORM; building materials; sulphur concrete; SOUTH;
D O I
10.3989/mc.2010.58910
中图分类号
TU [建筑科学];
学科分类号
0813 ;
摘要
Nowadays, alternative uses of phosphogypsum (PG) in the building industry are being considered in several countries; however, the natural radioactivity level in the PG could be a restriction for those uses. United States Environmental Protection Agency (US-EPA) classified PG as Technologically Enhanced Naturally Occurring Radioactive Material (TENORM). This drawback could be avoided controlling its percentage in the cement preparation and the radionuclides content in the other raw materials used in its production, and calculating the activity concentration index (I) in the final by-products. The valorization of PG as a building material has been studied, from a radiological point of view, by developing a new stabilisation/solidification process. PG is incorporated within a polymeric sulphur matrix, obtaining a concrete-like material, which presents lower natural radioactive content than the initial PG. The 226Ra content of this material ranged between 26-27 Bq.kg(-1) and it is quite similar to that of common Spanish building materials.
引用
收藏
页码:503 / 515
页数:13
相关论文
共 28 条
[1]   Radioecological study of an estuarine system located in the south of Spain [J].
Bolivar, JP ;
Garcia-Tenorio, R ;
Vaca, F .
WATER RESEARCH, 2000, 34 (11) :2941-2950
[2]   Radionuclide flow during the conversion of phosphogypsum to ammonium sulfate [J].
Burnett, WC ;
Schultz, MK ;
Hull, CD .
JOURNAL OF ENVIRONMENTAL RADIOACTIVITY, 1996, 32 (1-2) :33-51
[3]  
*COMM EUR COMM, 1990, OFFICIAL J L, V80
[4]  
*COUNC EUR COMM, 1989, OFFICIAL J L, V40
[5]   Utilization of phosphogypsum as raw and calcined material in manufacturing of building products [J].
Degirmenci, Nurhayat .
CONSTRUCTION AND BUILDING MATERIALS, 2008, 22 (08) :1857-1862
[6]   Characterization of phosphogypsum wastes associated with phosphoric acid and fertilizers production [J].
El Afifi, E. M. ;
Hilal, M. A. ;
Attallah, M. F. ;
El-Reefy, S. A. .
JOURNAL OF ENVIRONMENTAL RADIOACTIVITY, 2009, 100 (05) :407-412
[7]  
Elkhadiri I, 2003, MATER CONSTRUCC, V53, P57
[8]  
European Commission, 1999, 112 EUR COMM DIR GEN
[9]   DETERMINATION OF LOW LEVELS OF POLONIUM-210 IN ENVIRONMENTAL MATERIALS [J].
FLYNN, WW .
ANALYTICA CHIMICA ACTA, 1968, 43 (02) :221-&
[10]   Radiochemistry of Florida phosphogypsum [J].
Hull, CD ;
Burnett, WC .
JOURNAL OF ENVIRONMENTAL RADIOACTIVITY, 1996, 32 (03) :213-238