Determination of Castor Oil Molecular Weight by Vapour Pressure Osmometry Technique

被引:13
作者
Da Silva, Nivea De Lima [1 ]
Batistella, Cesar [1 ]
Maciel Filho, Rubens [1 ]
Wolf Maciel, Maria Regina [1 ]
机构
[1] Univ Estadual Campinas, Sch Chem Engn, Lab Separat Proc Dev, BR-13081970 Campinas, SP, Brazil
来源
ICHEAP-10: 10TH INTERNATIONAL CONFERENCE ON CHEMICAL AND PROCESS ENGINEERING, PTS 1-3 | 2011年 / 24卷
关键词
ESTERS;
D O I
10.3303/CET1124101
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Nowadays, the molecular weight of vegetable oil is usually determined by gas chromatography analysis (GC) because this analysis permits the calculation of the fatty acid composition of the vegetable oil. This work presents a method to measure the molecular weight of castor oil using vapour pressure osmometry technique (VPO) and compares the result with GC analysis and with data present in the open literature. The VPO and GC results found were 927.88 g/mol and 928.31 g/mol, respectively. The molecular weight of castor oil is 927 g/mol according to literature, therefore the VPO can be a powerful measurement technique. VPO presents an accurate and fast way to measure the molecular weight of vegetable oil.
引用
收藏
页码:601 / 606
页数:6
相关论文
共 14 条
[1]   Molecular weight of petroleum asphaltenes: A comparison between mass spectrometry and vapor pressure osmometry [J].
Acevedo, S ;
Gutierrez, LB ;
Negrin, G ;
Pereira, JC ;
Mendez, B ;
Delolme, F ;
Dessalces, G ;
Broseta, D .
ENERGY & FUELS, 2005, 19 (04) :1548-1560
[2]  
[Anonymous], LOS MESST GUID
[3]  
[Anonymous], 2007, KNAUER GUID VAP PRES
[4]  
[Anonymous], FATS OILS HDB
[5]   Properties of alkyl esters base on castor oil [J].
Cvengros, Jan ;
Paligova, Jarmila ;
Cvengrosova, Zuzana .
EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY, 2006, 108 (08) :629-635
[6]  
Eser S., 1999, DIV FUEL CHEM, V44, P768
[7]   ETHANOLYSIS OF RAPESEED OIL - QUANTITATION OF ETHYL-ESTERS, MONOGLYCERIDES, DIGLYCERIDES, AND TRIGLYCERIDES AND GLYCEROL BY HIGH-PERFORMANCE SIZE-EXCLUSION CHROMATOGRAPHY [J].
FILLIERES, R ;
BENJELLOUNMLAYAH, B ;
DELMAS, M .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1995, 72 (04) :427-432
[8]   Production and purification of biodiesel and glycerine, since vegetal oils and kinetic of vegetal oils transesterification reaction for wasted frying oil [J].
Gonzalez Garnica, Julian Alfredo ;
da Silva, Nivea de Lima ;
Wolf Maciel, Maria Regina .
ICHEAP-9: 9TH INTERNATIONAL CONFERENCE ON CHEMICAL AND PROCESS ENGINEERING, PTS 1-3, 2009, 17 :433-438
[9]   DENSITY-ESTIMATION FOR FATTY-ACIDS AND VEGETABLE-OILS BASED ON THEIR FATTY-ACID COMPOSITION [J].
HALVORSEN, JD ;
MAMMEL, WC ;
CLEMENTS, LD .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1993, 70 (09) :875-880
[10]   Some physical properties of castor oil esters and hydrogenated castor oil esters [J].
Kulkarni, MG ;
Sawant, SB .
EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY, 2003, 105 (05) :214-218