Influence of temperature on evolution of coaxial ZnO/Al2O3 one-dimensional heterostructures:: From core-shell nanowires to spinel nanotubes and porous nanowires

被引：76

作者：

Yang, Yang ^{[1
]}

Kim, Dong Sik ^{[1
]}

Knez, Mato ^{[1
]}

Scholz, Roland ^{[1
]}

Berger, Andreas ^{[1
]}

Pippel, Eckhard ^{[1
]}

Hesse, Dietrich ^{[1
]}

Goesele, Ulrich ^{[1
]}

Zacharias, Margit ^{[2
]}

机构：

[1] Max Planck Inst Microstruct Phys, D-06120 Halle, Germany

[2] Univ Freiburg, Fac Sci Appl, IMTEK, D-79110 Freiburg, Germany

来源：

JOURNAL OF PHYSICAL CHEMISTRY C | 2008年 / 112卷 / 11期

关键词：

D O I：

10.1021/jp710948j

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this paper, we present the influence of temperature on the Kirkendall effect-related evolution of coaxial ZnO/Al2O3 one-dimensional heterostructures based on a solid-state reaction. Controllable fabrication of spinel ZnAl2O4-based nanotubes and porous nanowires can step-by-step be achieved from ZnO/Al2O3 core-shell nanowires with a change in the reaction temperature. In particular, we demonstrate that the formation of completely hollow nanotubes in this system is not strictly limited to a fixed stoichiometry of ZnO/Al2O3 required for the spinel-forming reaction when an annealing temperature of 800 degrees C is employed. Combined with atomic layer deposition, the wall thickness of the formed nanotubes can be further precisely tailored and defined. Our finding provides an effective route to fabricate spinel nanotubes as well as nanotube arrays on a large scale.

引用

页码：4068 / 4074

页数：7

共 31 条

[1] THE SYSTEM MGO-MGAL2O4 [J].

ALPER, AM ;

MCNALLY, RN ;

RIBBE, PH ;

DOMAN, RC .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1962, 45 (06) :263-268

[2]

Birnboim A, 2001, J AM CERAM SOC, V84, P1315, DOI 10.1111/j.1151-2916.2001.tb00835.x

[3] Formation of hollow Ni2P nanoparticles based on the nanoscale Kirkendall effect [J].

Chiang, Ray-Kuang ;

Chiang, Ray-Tung .

INORGANIC CHEMISTRY, 2007, 46 (02) :369-371

[4] Carbon nanotubes as molecular quantum wires [J].

Dekker, C .

PHYSICS TODAY, 1999, 52 (05) :22-28

[5] Growth mechanism and characterization of zinc oxide microcages [J].

Fan, HJ ;

Scholz, R ;

Kolb, FM ;

Zacharias, M ;

Gösele, U .

SOLID STATE COMMUNICATIONS, 2004, 130 (08) :517-521

[6] Formation of nanotubes and hollow nanoparticles based on Kirkendall and diffusion processes:: A review [J].

Fan, Hong Jin ;

Goesele, Ulrich ;

Zacharias, Margit .

SMALL, 2007, 3 (10) :1660-1671

[7] Influence of surface diffusion on the formation of hollow nanostructures induced by the Kirkendall effect: The basic concept [J].

Fan, Hong Jin ;

Knez, Mato ;

Scholz, Roland ;

Hesse, Dietrich ;

Nielsch, Kornelius ;

Zacharias, Margit ;

Gosele, Ulrich .

NANO LETTERS, 2007, 7 (04) :993-997

[8] Monocrystalline spinel nanotube fabrication based on the Kirkendall effect [J].

Fan, Hong Jin ;

Knez, Mato ;

Scholz, Roland ;

Nielsch, Kornelius ;

Pippel, Eckhard ;

Hesse, Dietrich ;

Zacharias, Margit ;

Goesele, Ulrich .

NATURE MATERIALS, 2006, 5 (08) :627-631

[9] Single-crystal gallium nitride nanotubes [J].

Goldberger, J ;

He, RR ;

Zhang, YF ;

Lee, SW ;

Yan, HQ ;

Choi, HJ ;

Yang, PD .

NATURE, 2003, 422 (6932) :599-602

[10] FORMATION OF MG2TIO4 EPITAXIAL THIN-FILMS ON MGO BY SOLID-STATE REACTION [J].

HESSE, D ;

BETHGE, H .

JOURNAL OF CRYSTAL GROWTH, 1981, 52 (APR) :875-882

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