From ligands to binding motifs and beyond; the enhanced versatility of nanocrystal surfaces

被引:93
作者
De Roo, J. [1 ]
De Keukeleere, K. [1 ]
Hens, Z. [1 ]
Van Driessche, I. [1 ]
机构
[1] Univ Ghent, Dept Inorgan & Phys Chem, Krijgslaan 281 S3, B-9000 Ghent, Belgium
关键词
METAL-OXIDE NANOCRYSTALS; LEAD HALIDE PEROVSKITES; PBS QUANTUM DOTS; COLLOIDAL NANOCRYSTALS; CDSE NANOCRYSTALS; NMR-SPECTROSCOPY; EXCHANGE REACTIONS; CATION-EXCHANGE; ANION-EXCHANGE; CHEMISTRY;
D O I
10.1039/c6dt02410f
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Surface chemistry bridges the gap between nanocrystal synthesis and their applications. In this respect, the discovery of complex ligand binding motifs on semiconductor quantum dots and metal oxide nanocrystals opens a gateway to new areas of research. The implications are far-reaching, from catalytic model systems to the performance of solar cells.
引用
收藏
页码:13277 / 13283
页数:7
相关论文
共 87 条
  • [21] Carboxylic-Acid-Passivated Metal Oxide Nanocrystals: Ligand Exchange Characteristics of a New Binding Motif
    De Roo, Jonathan
    Justo, Yolanda
    De Keukeleere, Katrien
    Van den Broeck, Freya
    Martins, Jose C.
    Van Driessche, Isabel
    Hens, Zeger
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (22) : 6488 - 6491
  • [22] Unravelling the Surface Chemistry of Metal Oxide Nanocrystals, the Role of Acids and Bases
    De Roo, Jonathan
    Van den Broeck, Freya
    De Keukeleere, Katrien
    Martins, Jose C.
    Van Driessche, Isabel
    Hens, Zeger
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (27) : 9650 - 9657
  • [23] Surface Chemistry of CuInS2 Colloidal Nanocrystals, Tight Binding of L-Type Ligands
    Dierick, Ruben
    Van den Broeck, Freya
    De Nolf, Kim
    Zhao, Qiang
    Vantomme, Andre
    Martins, Jose C.
    Hens, Zeger
    [J]. CHEMISTRY OF MATERIALS, 2014, 26 (20) : 5950 - 5957
  • [24] Lead Halide Perovskites and Other Metal Halide Complexes As Inorganic Capping Ligands for Colloidal Nanocrystals
    Dirin, Dmitry N.
    Dreyfuss, Sebastien
    Bodnarchuk, Maryna I.
    Nedelcu, Georgian
    Papagiorgis, Paris
    Itskos, Grigorios
    Kovalenko, Maksym V.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (18) : 6550 - 6553
  • [25] A Generalized Ligand-Exchange Strategy Enabling Sequential Surface Functionalization of Colloidal Nanocrystals
    Dong, Angang
    Ye, Xingchen
    Chen, Jun
    Kang, Yijin
    Gordon, Thomas
    Kikkawa, James M.
    Murray, Christopher B.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (04) : 998 - 1006
  • [26] Doris SE, 2014, J AM CHEM SOC, V136, P15702, DOI [10.1021/ja508675t, 10.1021/ja508675T]
  • [27] Utilizing Self-Exchange To Address the Binding of Carboxylic Acid Ligands to CdSe Quantum Dots
    Fritzinger, Bernd
    Capek, Richard K.
    Lambert, Karel
    Martins, Jose C.
    Hens, Zeger
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (29) : 10195 - 10201
  • [28] In Situ Observation of Rapid Ligand Exchange in Colloidal Nanocrystal Suspensions Using Transfer NOE Nuclear Magnetic Resonance Spectroscopy
    Fritzinger, Bernd
    Moreels, Iwan
    Lommens, Petra
    Koole, Rolf
    Hens, Zeger
    Martins, Jose C.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (08) : 3024 - 3032
  • [29] Conversion Reactions of Cadmium Chalcogenide Nanocrystal Precursors
    Garcia-Rodriguez, Raul
    Hendricks, Mark P.
    Cossairt, Brandi M.
    Liu, Haitao
    Owen, Jonathan S.
    [J]. CHEMISTRY OF MATERIALS, 2013, 25 (08) : 1233 - 1249
  • [30] Large-scale synthesis of organophilic zirconia nanoparticles and their application in organic-inorganic nanocomposites for efficient volume holography
    Garnweitner, Georg
    Goldenberg, Leonid M.
    Sakhno, Oksana V.
    Antonietti, Markus
    Niederberger, Markus
    Stumpe, Joachim
    [J]. SMALL, 2007, 3 (09) : 1626 - 1632