From ligands to binding motifs and beyond; the enhanced versatility of nanocrystal surfaces

被引：95

作者：

De Roo, J. ^{[1
]}

De Keukeleere, K. ^{[1
]}

Hens, Z. ^{[1
]}

Van Driessche, I. ^{[1
]}

机构：

[1] Univ Ghent, Dept Inorgan & Phys Chem, Krijgslaan 281 S3, B-9000 Ghent, Belgium

来源：

DALTON TRANSACTIONS | 2016年 / 45卷 / 34期

关键词：

METAL-OXIDE NANOCRYSTALS; LEAD HALIDE PEROVSKITES; PBS QUANTUM DOTS; COLLOIDAL NANOCRYSTALS; CDSE NANOCRYSTALS; NMR-SPECTROSCOPY; EXCHANGE REACTIONS; CATION-EXCHANGE; ANION-EXCHANGE; CHEMISTRY;

D O I：

10.1039/c6dt02410f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Surface chemistry bridges the gap between nanocrystal synthesis and their applications. In this respect, the discovery of complex ligand binding motifs on semiconductor quantum dots and metal oxide nanocrystals opens a gateway to new areas of research. The implications are far-reaching, from catalytic model systems to the performance of solar cells.

引用

页码：13277 / 13283

页数：7

共 87 条

[1] Tuning the Optical Properties of Cesium Lead Halide Perovskite Nanocrystals by Anion Exchange Reactions [J].

Akkerman, Quinten A. ;

D'Innocenzo, Valerio ;

Accornero, Sara ;

Scarpellini, Alice ;

Petrozza, Annamaria ;

Prato, Mirko ;

Manna, Liberato .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (32) :10276-10281

[2] Ligand Exchange and the Stoichiometry of Metal Chalcogenide Nanocrystals: Spectroscopic Observation of Facile Metal-Carboxylate Displacement and Binding [J].

Anderson, Nicholas C. ;

Hendricks, Mark P. ;

Choi, Joshua J. ;

Owen, Jonathan S. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (49) :18536-18548

[3] Soluble, Chloride-Terminated CdSe Nanocrystals: Ligand Exchange Monitored by 1H and 31P NMR Spectroscopy [J].

Anderson, Nicholas C. ;

Owen, Jonathan S. .

CHEMISTRY OF MATERIALS, 2013, 25 (01) :69-76

[4] NMR analysis of surfaces and interfaces in 2-nm CdSe [J].

Berrettini, MG ;

Braun, G ;

Hu, JG ;

Strouse, GF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (22) :7063-7070

[5]

Boles MA, 2016, NAT MATER, V15, P141, DOI [10.1038/NMAT4526, 10.1038/nmat4526]

[6] Core and surface engineering in binary, ternary and quaternary semiconductor nanocrystals-A critical review [J].

Bujak, Piotr .

SYNTHETIC METALS, 2016, 222 :93-114

[7] Effect of Surface Stoichiometry on Blinking and Hole Trapping Dynamics in CdSe Nanocrystals [J].

Busby, Erik ;

Anderson, Nicholas C. ;

Owen, Jonathan S. ;

Sfeir, Matthew Y. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2015, 119 (49) :27797-27803

[8] Multigram scale, solventless, and diffusion-controlled route to highly monodisperse PbS nanocrystals [J].

Cademartiri, L ;

Bertolotti, J ;

Sapienza, R ;

Wiersma, DS ;

von Freymann, G ;

Ozin, GA .

JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (02) :671-673

[9] Synthesis and Surface Chemistry of Cadmium Carboxylate Passivated CdTe Nanocrystals from Cadmium bis(Phenyltellurolate) [J].

Campos, Michael P. ;

Owen, Jonathan S. .

CHEMISTRY OF MATERIALS, 2016, 28 (01) :227-233

[10] Colloidal Quantum Dot Solar Cells [J].

Carey, Graham H. ;

Abdelhady, Ahmed L. ;

Ning, Zhijun ;

Thon, Susanna M. ;

Bakr, Osman M. ;

Sargent, Edward H. .

CHEMICAL REVIEWS, 2015, 115 (23) :12732-12763

← 1 2 3 4 5 6 7 8 9 →