Modulation of Trivalent/Tetravalent Metallic Elements in Ni-Based Layered Double Hydroxides for Photocatalytic CO2 Reduction

被引:21
作者
Wang, Ruonan [1 ]
Wang, Xinyi [2 ,3 ]
Xiong, Yongheng [1 ]
Hou, Yuyan [1 ]
Wang, Yaxuan [1 ]
Ding, Jie [1 ]
Zhong, Qin [1 ]
机构
[1] Nanjing Univ Sci & Technol, Sch Chem & Chem Engn, Nanjing 210094, Jiangsu, Peoples R China
[2] Shandong First Med Univ, Sch Nursing, Tai An 271016, Shandong, Peoples R China
[3] Shandong Acad Med Sci, Tai An 271016, Shandong, Peoples R China
基金
中国国家自然科学基金;
关键词
photocatalysis; CO2; layered double hydroxides; in situ DRIFTS; CHARGE-TRANSFER; ACTIVE-SITES; TIO2; H2O; HETEROJUNCTION; PHOTOREDUCTION; IDENTIFICATION; PERFORMANCE; INTERFACE; EVOLUTION;
D O I
10.1021/acsami.2c07940
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Herein, by modulating trivalent/tetravalent metallic elements, NiMLDHs (M = Al, Co, Fe, Mn, and Ti) were successfully prepared and evaluated in photocatalytic CO(2 )reduction reaction (PCRR). Photocatalytic results declared that the electronic yields followed the order of NiTiLDH > NiCoLDH > NiFeLDH > NiMnLDH > NiAlLDH. Multiple characterizations affirmed that the introduction of various trivalent/tetravalent metallic elements could visibly affect the three critical aspects: (i) light harvesting; (ii) charge separation and transfer; and (iii) surface reactions, thus governing PCRR performance. Importantly, an in-depth mechanistic investigation was conducted by in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) experiments. These layered double hydroxides (LDHs) exhibited different adsorption/activation behaviors toward CO2 molecule: NiAlLDH primarily converted CO2 into b-CO32- species; NiCoLDH, NiFeLDH, and NiMnLDH could induce c-CO32- intermediate; NiTiLDH could generate a higher proportion of (CO2)-C-center dot- species, which was an important intermediate to produce CO. More favorable carries separation and adsorption/activation process was presented upon NiTiLDH, thus more markedly enhancing photoactivity.
引用
收藏
页码:35654 / 35662
页数:9
相关论文
共 49 条
[1]   Bifunctional TiO2 underlayer for α-Fe2O3 nanorod based photoelectrochemical cells: enhanced interface and Ti4+ doping [J].
Annamalai, Alagappan ;
Shinde, Pravin S. ;
Subramanian, Arunprabaharan ;
Kim, Jae Young ;
Kim, Jin Hyun ;
Choi, Sun Hee ;
Lee, Jae Sung ;
Jang, Jum Suk .
JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (09) :5007-5013
[2]   Carbon dioxide adsorption on oxide nanoparticle surfaces [J].
Baltrusaitis, Jonas ;
Schuttlefield, Jennifer ;
Zeitler, Elizabeth ;
Grassian, Vicki H. .
CHEMICAL ENGINEERING JOURNAL, 2011, 170 (2-3) :471-481
[3]   Metal-Free Catalysis: A Redox-Active Donor-Acceptor Conjugated Microporous Polymer for Selective Visible-Light-Driven CO2 Reduction to CH4 [J].
Barman, Soumitra ;
Singh, Ashish ;
Rahimi, Faruk Ahamed ;
Maji, Tapas Kumar .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2021, 143 (39) :16284-16292
[4]   Layered double hydroxide-based photocatalytic materials toward renewable solar fuels production [J].
Bian, Xuanang ;
Zhang, Shuai ;
Zhao, Yunxuan ;
Shi, Run ;
Zhang, Tierui .
INFOMAT, 2021, 3 (07) :719-738
[5]   Recent advances in engineering active sites for photocatalytic CO2reduction [J].
Bo, Yanan ;
Gao, Chao ;
Xiong, Yujie .
NANOSCALE, 2020, 12 (23) :12196-12209
[6]   INFRARED SPECTROSCOPIC IDENTIFICATION OF SPECIES ARISING FROM REACTIVE ADSORPTION OF CARBON OXIDES ON METAL-OXIDE SURFACES [J].
BUSCA, G ;
LORENZELLI, V .
MATERIALS CHEMISTRY, 1982, 7 (01) :89-126
[7]   CO2 photo-reduction: insights into CO2 activation and reaction on surfaces of photocatalysts [J].
Chang, Xiaoxia ;
Wang, Tuo ;
Gong, Jinlong .
ENERGY & ENVIRONMENTAL SCIENCE, 2016, 9 (07) :2177-2196
[8]   Two-dimensional nanomaterials for photocatalytic CO2 reduction to solar fuels [J].
Chen, Yong ;
Jia, Gan ;
Hu, Yingfei ;
Fan, Guozheng ;
Tsang, Yuen Hong ;
Li, Zhaosheng ;
Zou, Zhigang .
SUSTAINABLE ENERGY & FUELS, 2017, 1 (09) :1875-1898
[9]   Dynamic charge transfer through Fermi level equilibration in the p-CuFe2O4/n-NiAl LDH interface towards photocatalytic application [J].
Das, Snehaprava ;
Patnaik, Sulagna ;
Parida, Kulamani .
CATALYSIS SCIENCE & TECHNOLOGY, 2020, 10 (18) :6285-6298
[10]   Insight into synergetic mechanism of Au@Pd and oxygen vacancy sites for coupling light-driven H2O oxidation and CO2 reduction [J].
Fan, Jiaxuan ;
Cheng, Lingxiang ;
Liu, Yanan ;
He, Yufei ;
Wang, Yanfei ;
Li, Dianqing ;
Feng, Junting .
JOURNAL OF CATALYSIS, 2019, 378 :164-175