Porpholactams and chlorolactams: replacement of a β,β′-double bond in meso-tetraphenyl-porphyrin and -chlorin by a lactam moiety

被引：22

作者：

Akhigbe, Joshua ^{[1
]}

Haskoor, John ^{[1
]}

Zeller, Matthias ^{[2
]}

Brueckner, Christian ^{[1
]}

机构：

[1] Univ Connecticut, Dept Chem, Storrs, CT 06269 USA

[2] Youngstown State Univ, Dept Chem, Youngstown, OH 44555 USA

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 30期

基金：

美国国家科学基金会;

关键词：

COMPLEXES; CONFUSION; CHEMISTRY; COMPOUND; POSITION; BASE;

D O I：

10.1039/c1cc12955d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of meso-tetraphenylporpholactone with hydrazine converts the lactone moiety to an N-aminolactam. It also reduces the opposite pyrrolic moiety of both the starting material and the N-aminolactam, generating chlorin-like chlorolactone and N-aminochlorolactam, respectively. Reductive N-N cleavage of the N-aminoporpholactam generates the parent porpholactam.

引用

收藏

页码：8599 / 8601

页数：3

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