Long-Chain Polyhydroxyesters from Natural Occurring Aleuritic Acid as Potential Material for Food Packaging

被引:20
作者
Benitez, Jose Jesus [1 ]
Alejandro Heredia-Guerrero, Jose [2 ]
Guzman-Puyol, Susana [2 ]
Dominguez, Eva [3 ]
Heredia, Antonio [4 ]
机构
[1] Univ Seville, ICMS, CSIC, Ctr Mixto, E-41092 Seville, Spain
[2] Fdn Ist Italiano Tecnol IIT, Smart Mat, Nanophys, Genoa, Italy
[3] Univ Malaga, CSIC, Inst Hortofruticultura Subtrop & Mediterranea IHS, E-29071 Malaga, Spain
[4] Univ Malaga, UMA CSIC, IHSM La Mayora, Dept Bioquim & Biol Mol, E-29071 Malaga, Spain
关键词
Biomimetic polymers; Food packaging; Renewable polyesters; 10,16-DIHYDROXYHEXADECANOIC ACID; SPECTRA;
D O I
10.1080/1539445X.2014.993476
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Fatty polyhydroxyesters (C >= 16) are present in nature as barrier polymers like cutin in some protective tissues of higher plants. The mimicry of these biopolymers is regarded as a strategy to design nontoxic and fully biodegradable food packaging films and coatings. To obtain cutin inspired materials we have used a natural occurring polyhydroxylated monomer like aleuritic (9,10,16-trihydroxypalmitic) acid and a direct and scalable synthesis route consisting in the noncatalyzed melt-condensation polymerization in air. To reduce the number of hydroxyl groups and to increase hydrophobicity, palmitic acid has been used as a capping agent. Aleuritic-palmitic polyhydroxyesteres films have been obtained and characterized.
引用
收藏
页码:5 / 11
页数:7
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