Reaction of 1,1'-bis(alkylaminomethylene)ferrocenes with benzoylisothiocyanate

被引：5

作者：

Richter, R

Seidelmann, O

Beyer, L

Plenio, H

机构：

[1] UNIV LEIPZIG,INST ANORGAN CHEM,D-04103 LEIPZIG,GERMANY

[2] UNIV FREIBURG,INST ANORGAN & ANALYT CHEM,D-79104 FREIBURG,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 525卷 / 1-2期

关键词：

ferrocene; ferrocenophane; thiourea; crystal structure; thiocyanate;

D O I：

10.1016/S0022-328X(96)06502-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of 1,1'-bis((n)butylaminomethylene)ferrocene with two equivalents of benzoyl isothiocyanate yields 1,1'-ferrocenediyl-bis(N-methylene-N-(n)butyl-N'-benzoyl thiourea). In contrast, the respective reaction with 1,1'-bis(ethylaminomethylene)ferrocene leads to 2-N-ethylammonium-[3]-1,1'-ferrocenophane thiocyanate. Both compounds are characterized by X-ray structure determination. A possible reaction mechanism is discussed.

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收藏

页码：199 / 205

页数：7

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