Synthesis of (1R,1R')-2,6-bis[1-(diphenylphosphino)ethyl]pyridine and its application in asymmetric transfer hydrogenation

被引：118

作者：

Jiang, QZ ^{[1
]}

VanPlew, D ^{[1
]}

Murtuza, S ^{[1
]}

Zhang, XM ^{[1
]}

机构：

[1] PENN STATE UNIV,DEPT CHEM,UNIVERSITY PK,PA 16802

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 06期

关键词：

D O I：

10.1016/0040-4039(95)02298-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A C-2 symmetric tridentate ligand, (1R, 1R') 2,6-Bis[1-(diphenylphosphino)ethyl]pyridine, has been synthesized in enantiomerically pure form. A practical method to synthesize a variety of chiral pyridyl diols is reported. Asymmetric transfer hydrogenation is achieved using the tridentate ligand.

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收藏

页码：797 / 800

页数：4

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