Modification of wetting properties of PMMA by Immersion Plasma Ion Implantation

被引:3
作者
Mireault, N. [1 ]
Ross, G. G. [1 ]
机构
[1] Univ Quebec, INRS Energie Mat & Telecommun, Varennes, PQ J3X 1S2, Canada
关键词
PMMA; wetting; immersion plasma ion implantation; CD-XPS; contact angle hysteresis;
D O I
10.1142/S0218625X08011470
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Advancing and receding contact angles below 5 degrees have been obtained on PMMA surfaces with the implantation of argon and oxygen ions. The ion implantations were performed by means of the Immersion Plasma Ion Implantation (IPII) technique, a hybrid between ion beams and immersion plasmas. Characterization of treated PMMA surfaces by means of XPS and its combination with chemical derivatization (CD-XPS) have revealed the depletion of oxygen and the creation of dangling bonds, together with the formation of new chemical functions such as -OOH, -COOH and C=C. These observations provide a good explanation for the strong increase of the wetting properties of the PMMA surfaces.
引用
收藏
页码:345 / 354
页数:10
相关论文
共 67 条
  • [1] Alexander MR, 1996, SURF INTERFACE ANAL, V24, P217
  • [2] ANDRADE JD, 1983, SURFACE CHEM PHYS, V1
  • [3] ANDRADE JD, 1983, PHYSICOCHEMICAL ASPE
  • [4] THE EXPERIMENTAL TEST OF A MICROWAVE ION-BEAM SOURCE IN OXYGEN
    ASMUSSEN, J
    DAHIMENE, M
    [J]. JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 1987, 5 (01): : 328 - 331
  • [5] INSITU POLYMERIZATION OF VINYL MONOMERS IN POLYESTER YARNS
    AVNY, Y
    REBENFELD, L
    WEIGMANN, HD
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 1978, 22 (01) : 125 - 147
  • [6] DEPTH SENSITIVITY OF WETTING - MONOLAYERS OF OMEGA-MERCAPTO ETHERS ON GOLD
    BAIN, CD
    WHITESIDES, GM
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (17) : 5897 - 5898
  • [7] BASZKIN A, 1971, J POLYM SCI C, V34, P243
  • [8] CHEMICAL DERIVATIZATION AND SURFACE-ANALYSIS
    BATICH, CD
    [J]. APPLIED SURFACE SCIENCE, 1988, 32 (1-2) : 57 - 73
  • [9] SURFACE MODIFICATION OF POLYETHYLENE BY ELECTRICAL-DISCHARGE TREATMENT AND THE MECHANISM OF AUTO-ADHESION
    BLYTHE, AR
    BRIGGS, D
    KENDALL, CR
    RANCE, DG
    ZICHY, VJI
    [J]. POLYMER, 1978, 19 (11) : 1273 - 1278
  • [10] Optimum tribological improvement of aluminum using oxygen plasma source ion implantation
    Bolduc, M
    Terreault, B
    Reguer, A
    Shaffer, E
    St-Jacques, RG
    [J]. JOURNAL OF MATERIALS RESEARCH, 2003, 18 (08) : 1761 - 1764