catena-Poly[[aquabis{4-[2-(2,4-dioxopentan-3-ylidene)hydrazin-1-yl]benzoato-κO}copper(II)]-μ-N,N-diethylpyridine-3-carboxamide-κ2N1:O]

被引：4
|
作者：
Maharramov, Abel M. [3 ]
Mardanova, Vusala I. [3 ]
Chyraqov, Famil M. [3 ]
Gurbanov, Atash V. [3 ]
Ng, Seik Weng [1 ,2 ]
机构：
[1] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia
[2] King Abdulaziz Univ, Fac Sci, Dept Chem, Jeddah 21413, Saudi Arabia
[3] Baku State Univ, Dept Organ Chem, Baku, Azerbaijan
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2012年 / 68卷
关键词：
data-to-parameter ratio = 18.4; mean σ(C-C) = 0.004 Å; R factor = 0.045; single-crystal X-ray study; T = 296 K; wR factor = 0.131;
D O I：
10.1107/S1600536812000025
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The Cu-II atom in the title compound, [Cu(C12H11N2O4)(2)(C10H14N2O)(H2O)](n), lies in a square plane defined by the O atoms of the carboxylate ions, the N atom of the N-heterocycle and the water molecule. Coordination by an amido O atom of an adjacent N-heterocycle in the apical direction leads to a polymeric chain running along [011]. The chain motif is consolidated by hydrogen bonds involving the water molecule; the water molecule is a hydrogen-bond donor to the free carbonyl atoms of the carboxylate ions. Intramolecular N-H center dot center dot center dot O hydrogen bonds also occur.
引用
收藏
页码：M128 / U485
页数：12
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