catena-Poly[[aquabis{4-[2-(2,4-dioxopentan-3-ylidene)hydrazin-1-yl]benzoato-κO}copper(II)]-μ-N,N-diethylpyridine-3-carboxamide-κ2N1:O]

被引：4

作者：

Maharramov, Abel M. ^{[3
]}

Mardanova, Vusala I. ^{[3
]}

Chyraqov, Famil M. ^{[3
]}

Gurbanov, Atash V. ^{[3
]}

Ng, Seik Weng ^{[1
,2
]}

机构：

[1] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia

[2] King Abdulaziz Univ, Fac Sci, Dept Chem, Jeddah 21413, Saudi Arabia

[3] Baku State Univ, Dept Organ Chem, Baku, Azerbaijan

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2012年 / 68卷

关键词：

data-to-parameter ratio = 18.4; mean σ(C-C) = 0.004 Å; R factor = 0.045; single-crystal X-ray study; T = 296 K; wR factor = 0.131;

D O I：

10.1107/S1600536812000025

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The Cu-II atom in the title compound, [Cu(C12H11N2O4)(2)(C10H14N2O)(H2O)](n), lies in a square plane defined by the O atoms of the carboxylate ions, the N atom of the N-heterocycle and the water molecule. Coordination by an amido O atom of an adjacent N-heterocycle in the apical direction leads to a polymeric chain running along [011]. The chain motif is consolidated by hydrogen bonds involving the water molecule; the water molecule is a hydrogen-bond donor to the free carbonyl atoms of the carboxylate ions. Intramolecular N-H center dot center dot center dot O hydrogen bonds also occur.

引用

页码：M128 / U485

页数：12

共 6 条

[1]

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[2]

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Maharramov, Abel M. ;

Mardanova, Vusala I. ;

Chyraqov, Famil ;

Gurbanov, Atash V. ;

Ng, Seik Weng .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 :M708-U656

[4]

Sheldrick G.M., 1996, SADABS

[5] A short history of SHELX [J].

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ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122

[6] publCIF: software for editing, validating and formatting crystallographic information files [J].

Westrip, Simon P. .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2010, 43 :920-925

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