Porous, Fluorescent, Covalent Triazine-Based Frameworks Via Room-Temperature and Microwave-Assisted Synthesis

被引：660
作者：
Ren, Shijie [1 ,2 ]
Bojdys, Michael J. [1 ,2 ]
Dawson, Robert [1 ,2 ]
Laybourn, Andrea [1 ,2 ]
Khimyak, Yaroslav Z. [3 ]
Adams, Dave J. [1 ,2 ]
Cooper, Andrew I. [1 ,2 ]
机构：
[1] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England
[2] Univ Liverpool, Ctr Mat, Liverpool L69 7ZD, Merseyside, England
[3] Univ E Anglia, Sch Pharm, Norwich NR4 7TJ, Norfolk, England
来源：
ADVANCED MATERIALS | 2012年 / 24卷 / 17期
基金：
英国工程与自然科学研究理事会;
关键词：
covalent frameworks; microporous organic polymers; triazine; MICROPOROUS POLYMER NETWORKS; GRAPHITIC CARBON NITRIDE; ORGANIC FRAMEWORKS; HYDROGEN STORAGE; SURFACE-AREA; IONOTHERMAL SYNTHESIS; 1,3,5-TRIAZINE; CRYSTALLINE; STABILITY; CATALYSIS;
D O I：
10.1002/adma.201200751
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Porous, fluorescent, covalent triazine-based frameworks (CTFs) are obtained in an unprecedentedly mild reaction, opening up a scalable pathway for molecular building blocks previously thought incompatible with this chemistry. Choice of monomers and synthetic conditions determines the optical properties and nano-scale ordering of these highly microporous materials with BET surface areas exceeding 1100 m 2 g -1 and exceptional CO 2 capacities (up to 4.17 mmol g -1). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：2357 / 2361
页数：5
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