Reduction of Aromatic and Aliphatic Esters Using the Reducing Systems MoO2(acac)2 or V(O)(OiPr)3 in Combination with 1,1,3,3-Tetramethyldisiloxane

被引：38

作者：

Pehlivan, Leyla ^{[1
]}

Metay, Estelle ^{[1
]}

Laval, Stephane ^{[1
]}

Dayoub, Wissam ^{[1
]}

Delbrayelle, Dominique ^{[2
]}

Mignani, Gerard ^{[3
]}

Lemaire, Marc ^{[1
]}

机构：

[1] Univ Lyon 1, Lab Catalyse & Synth Organ, ICBMS, CNRS,UMR 5246, F-69622 Villeurbanne, France

[2] Minakem SAS, F-59310 Beuvry La Foret, France

[3] Rhodia, Lyon Res Ctr, F-69192 St Fons, France

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 2011卷 / 36期

关键词：

Synthetic methods; Reduction; Esters; Siloxanes; Molybdenum; Vana-dium; TITANOCENE-CATALYZED REDUCTION; CARBOXYLIC ESTERS; SELECTIVE REDUCTION; CHEMOSELECTIVE REDUCTION; EFFICIENT SYSTEM; ALCOHOLS; HYDROSILYLATION; LACTONES; ACIDS; POLYMETHYLHYDROSILOXANE;

D O I：

10.1002/ejoc.201101016

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient reduction of aromatic and aliphatic esters with 1,1,3,3-tetramethyldisiloxane in combination with [MoO2(acac)2] or [V(O)(OiPr)3] is reported. In the former system, the presence of triphenylphosphane oxide allows high conversion and good isolated yield to be reached. For the latter system, no ligand is necessary to obtain the corresponding alcohols with similar results.

引用

页码：7400 / 7406

页数：7

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