Grignard Reagents and Non-Precious Metals: Cheap and Eco-Friendly Reagents for Developing Industrial Cross-Couplings. A Personal Account

被引：39

作者：

Cahiez, Gerard ^{[1
]}

Moyeux, Alban ^{[1
,2
]}

Cossy, Janine ^{[3
]}

机构：

[1] PSL Res Univ, CNRS, Inst Rech Chim Paris, UMR 8247,Chim ParisTech, F-75005 Paris, France

[2] Univ Paris 13, UFR SMBH, Sorbonne Paris Cite, F-93017 Bobigny, France

[3] PSL Res Univ, Inst Chem Biol & Innovat CBI ESPCI ParisTech, Lab Chim Organ, CNRS,UMR 8231, F-75231 Paris 05, France

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2015年 / 357卷 / 09期

关键词：

catalysis; cobalt; copper; cross-coupling; Grignard reagents; iron; manganese; non-precious metals; silver; SECONDARY ALKYL-HALIDES; ORGANOMAGNESIUM REAGENTS; ALKENYL HALIDES; IRON; ARYL; MAGNESIUM; CHLORIDES; COMPLEXES; CATALYSIS; TERTIARY;

D O I：

10.1002/adsc.201400654

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Grignard reagents are probably the best organometallics to develop large-scale eco-friendly cross-couplings compatible with the requirements of sustainable development. This account aims to highlight some reactions having an interesting industrial potential and gives the personal point of view of the authors on some attractive fields of research in this area.

引用

页码：1983 / 1989

页数：7