Total Synthesis of Polygalolide A

被引：8

作者：

Adachi, Masaatsu ^{[1
]}

Yamada, Hitomi ^{[1
]}

Isobe, Minoru ^{[2
]}

Nishikawat, Toshio ^{[1
]}

机构：

[1] Nagoya Univ, Grad Sch Bioagr Sci, Organ Chem Lab, Chikusa Ku, Nagoya, Aichi 4648601, Japan

[2] Natl Tsing Hua Univ, Dept Chem, Hsinchu 30013, Taiwan

来源：

ORGANIC LETTERS | 2011年 / 13卷 / 24期

基金：

日本学术振兴会;

关键词：

INTRAMOLECULAR-C-ARYLATION; SECONDARY ALCOHOLS; GLYCOSIDATION; CYCLOADDITION; ALKYNYL; TRIBUTYLPHOSPHINE; DEOXYGENATION; EPIMERIZATION; COMPLEXES; PRODUCTS;

D O I：

10.1021/ol2028256

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The total synthesis of polygalolide A was accomplished through intramolecular C-glycosylation of glucal modified with siloxyfuran. The siloxyfuran group and siloxy substituent at the C-3 position played crucial roles in allowing direct access to the highly substituted oxabicyclo[3.2.1] core skeleton with correct quaternary stereogenic centers.

引用

页码：6532 / 6535

页数：4

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